聚对羟基苯乙烯对聚偏氟乙烯-三氟乙烯结晶行为及铁电性能影响的研究-材料科学与工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 2．压电响应力显微镜 2．压电响应力显微镜(PFM)结果表明所制备薄膜具有很强的自发 极化能力且极化方向垂直于基底取向，氟原子倾向于在薄膜表面富集；且 冷结晶的处理方法能够使样品具有最佳的铁电性能。PVPh的加入，使得 薄膜的矫顽电压略有增大。共混物制成的三明治型电容器测试结果表明， PVPh的加入虽然降低了材料的极化强度但也显著降低了器件的漏电流密 度。通过介电谱仪的测试发现，PVPh也有助于降低共混膜的介电损耗。 通过共混改性的方法，得到了综合性能优异的铁电材料。 关键词：聚偏氟乙烯一三氟乙烯，聚对羟基苯乙烯，共混，居里相转变， 介电性能，铁电性能 II 万方数据 ABSTRACTTHE ABSTRACT THE RESEARCH OF EFFECT OF POLY(VINYL PHENOL) ON CRYSTALLIZATIoN BEHAVIOR AND FERROELECTRIC PERFORMANCE OF POLY(VINYLIDENE FLURIDE—TRIFLUROETHYLENE) ABSTRACT Among polymer ferroelectric materials，P(VDF—TrFE)is widely used ferroelectric polymer memories with its excellent processability，excellent chemical stability and a high spontaneous polarization．However,its high surface roughness，high leakage and low thermal stability,which limit the commercial applications of P(VDF-TrFE)．In this paper,a small amount of a low dielectric constant polymer PVPh was added to the P(VDF—TrFEl obtained P(VDF—TrFE)／PVPh blends．we will study the effect of PVPh on P(VDF—TrFE)from two perspectives including crystallization behavior and electrical properties． 1．We prepared a stable phase separation structure of the P(VDF—TrFE)／PVPh blend film，the accession of the PVPh leaded to the grain size of P(VDF—TrFE)and the roughness of the P(VDF—TrFE)／PVPh blend film 万方数据 万方数据 万方数据 北京化工大学硕士学位论文decrease 北京化工大学硕士学位论文 decrease．The PVPh with spherical morphology distributed in blends．With the increase of the content of the PVPh．the size of PVPh increased．The addition of PVPh improved the thermal stability of P(VDF-TrFE)．A small amount of PVPh(when the concentration of PVPh was 5％or less)did not affect the Curie phase transition temperature of P(VDF·TrFE)；a further increase of the content of PVPh(when the concentration of PVPh increased to l 0％)，will reduce the Curie transition temperature of P(VDF-TrFE)． 2．The results of PFM show that the polarized b-axis of the ferroelectric crystal orientated perpendicular to the substrate，and the method of the cold crystallization treatment enabled