反相气相色谱法研究CPC2膨润土对VOCs的吸附作用-环境科学学报.PDF

第 23 卷第 4 期 环 　境 　科 　学 　学 　报 Vol . 23 ,No . 4 2003 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE Jul . ,2003 ( ) 文章编号 2003 　　　中图分类号 :X132 　　　文献标识码 :A 反相气相色谱法研究 CPC膨润土对 VOCs 的 吸附作用 ( ) 田森林 ,朱利中 ,施 　耀　浙江大学环境与资源学院 ,杭州 　310028 摘要 :运用反相气相色谱法研究了20 种 VOCs 在 CPC膨润土上的吸附平衡及吸附热. 结果表明,CPC膨润土对 VOCs 的吸附 有较强选择性 ,吸附能力与有机物的分子量 、分子结构 、饱和蒸气压等物理化学性质有关 ,对苯系物和分子量较大的酯类和 酮类等吸附能力较强. 温度较低时 ,CPC膨润土对VOCs 的吸附能力较强 ,吸附热较大 ;吸附热与VOCs 的沸点蒸发热相当 ,但 比活性炭等常规吸附剂对 VOCs 的吸附热小. 关键词 :有机膨润土 ;吸附;挥发性有机物 ;反相气相色谱 Study on sorption characterization of VOCs onto CPCbentonite by inverse gas chromatography ( TIAN Senlin , ZHU Lizhong , SHI Yao 　 College of Environmental and Resource Sciences , Zhejiang University , Hangzhou 　 310028 , China) Abstract :Sorption properties and enthalpies of 20 VOCs onto CPCorganobentonite were studied by inverse gas chromatography. CPCbentonite showed strong selectivity toward VOCs , and its sorption capacity depended on physicochemical properties of VOCs , such as molecular weight , structure , and saturated vapor pressure . The sorption abilities of BTEX , esters and ketones with greater molecular weights to CPCbentonite were greater than the others. The sorption properties were obviously influenced by temperature . The sorption enthalpies of VOCs onto CPC bentonite were similar fo heating of evaporation , but smaller than that of common adsorbents. Keywords :organobentonite ; sorption ; volatile organic compounds ; inverse gas chromatography 与膨润土原土相比,有机膨润土有机碳含量增加 、疏水性提高 、对有机物吸附能力增强 ,在 有机废水 、废气吸附处理和土壤 、地下水污染修复中有很好的应用前景. 但迄今研究得最多的