不同形貌mos2纳米材料的制备及其电化学性能物理化学专业论文.docxVIP

不同形貌MoS2纳米材料的制备及其电化学性能的层间距增大至0．97 不同形貌MoS2纳米材料的制备及其电化学性能 的层间距增大至0．97 nlTI。该结构可以有效防止rGO纳米片的堆积和聚集，并且为锂离 子的传输提供更加有利的传输路径，从而减小了传输阻力。GL．MoS2／rGO纳米复合材料 作为锂电池负极材料显示出良好的循环稳定性和倍率性能。在500 mA g。1电流密度下， 循环100次后可逆容量保持在908 mAh g～。 关键词：纳米材料；二硫化钼；复合材料；负极材料；电化学性能； 万方数据 大连理工大学博士学位论文AB 大连理工大学博士学位论文 AB STRACT Two．dimensional(2D)layered transition metal dichalcogenides(TMDs)have received much attention in recent years due to their unique physical and chemical properties．MoS2， as one member of TMDs with a typical hexagonal layered structure，has strong covalent forces within the layers while van der Waals interaction enables stacking of the layers． Particularly，MoS2 nanomaterials exhibit a wide range of unique electrical，optical and excellent catalytic properties that do not exist in their bulk counterparts．Because of the structural anisotropy，different morphology and structure will affect the performances significantly．Developing new methods to prepare different structural and morphological MoS2 and MoS2-based composites is under any circumstances of vital importance for the extension of the applications in all fields．Based on above reasons，the thesis aims to synthesis of MoS2 with different structure and morphology，and introduction of high conductive graphene on the purpose of improving the overall electrochemical performance of MoS2．Effects of the structure and morphology on the electrochemical performance of MoS2 are also investigated． In the beginning．convenient synthetic route for the preparation of the amorphous MoS2 by one．pot solvothermal method was provided．MoS2 nanosphere and MoS2 nanoflower were prepared by using different template agents，furthermore，a novel strategy to fabricate 1．D MoS，nanorods was developed by a facial one．step solvothermal method without addding any template and surfactant．Synthesis of graphene·like MoS2 flakes and tunable layers can be easily controlled by the thermal decomposition temperature of a single source precusor．Then，GL．MoS2／rGO was synthesized by