制备方法 过渡金属掺杂对pd四cza催化剂三效性能影响的研究.docx

摘要 关键词:三效催化剂，过渡金属，铺错固熔体，热稳定性，汽车尾气净化 V 摘要Abstract 摘要 Abstract The problem of pollutants emitted by vehicles have received the widespread attention in the society．The application of catalytic invert technique is the most effective method to realize automotive eahaust purification(over Euro—IV standard)． High performance thulium modified alumina material(ACZO)is the pivotal component in the catalysts of automotive exhaust purification，and it has been applied in practice．As the redox reaction of three way catalyst mainly take place in the catalysts’surface，the high surface and high thermal stability of high performance ACZO material is the precondition of high oxygen-storage capacity．Recently to satisfy the catalyst’S cold—starting performance，catalytic invert instrument is near to the vent of the engine during pratical application．This measure needs to have better performance of high thermal stability and large surface area．7-A1203 is one of supports of the catalysts which are the most far—ranging application．But the problem of thermal stability of 7一A1203 is a long—term one，which people is puzzled，especially in the atmosphere of high temperature and vapour being present at．A1203 is easy to take place phase transition and sinter，and it evolves to ct-phase being steady in thermodynamics and large particle causing a drastic decrease in the surface area．This is one of important reasons which contribute to the thermal deactivation of the catalysts．Therefore，investigation and exploitation of new thulium modified alumina material with high thermal stability and high surface area has importantly academic and practical significance for improving durability and cold—starting performance of three-way catalysts for automotive exhaust purification． In this work，the effects of prepared method，transition metals(Cr、Mn、Fe、 Co and Ni)，preparation condition on CZA material and the effect of catalysts are discussed in detail．The CZA supports are synthesized by five different methods，