钙钛矿太阳能电池中电子空穴传输层的研究化学工程与技术专业论文.docxVIP

北京化工大学硕士学位论文的光电转化效率，体异质结钙钛矿电池获得13．04％的光电转化效率。 北京化工大学硕士学位论文 的光电转化效率，体异质结钙钛矿电池获得13．04％的光电转化效率。 高效钙钛矿电池大多以二氧化钛为致密层，然而二氧化钛的光学 和电学性质存在缺陷。在本文中首次通过钌掺杂改善二氧化钛光电性 质，并以CH3NH3Pbl3dfix为吸光层制备了平面异质结钙钛矿电池。 钌掺杂比例影响着器件性能，当掺杂浓度为0．01M时获得电池最高光 电转化效率为15．70％，而未掺杂器件效率最高仅为13．42％。整流曲 线表明了掺杂后致密层的整流效果增强。通过紫外可见光谱和紫外电 子能谱表征了掺杂后半导体材料导带位置上移，使其与 CH3NH3Pbl3哨C1J的导带更加匹配，减小了能量损失。通过电化学阻抗 谱表征了掺杂后器件的串联电阻减小，并联电阻增大。降低的串联电 阻表明电荷更加有效的正向传输，提高的并联电阻表明了更少的电子 空穴复合。在本文中也对新型致密层进行了初步的探究，成功制备了 锌锡氧多元氧化物。通过优化锌锡比例，制备出以CH3NH3Pbl3。fix 为吸光层的钙钛矿电池获得最高光电转化效率达到9．58％，证明了锌 锡氧三元氧化物可以作为致密层应用于钙钛矿电池之中。 钙钛矿电池大多以Spiro—MeOTAD为空穴传输层，但其价格昂贵， 并不是理想的空穴传输材料。因此在本文尝试采用廉价碘化亚铜为无 机空穴传输层，以电化学沉积的方法制备碘化亚铜薄膜。并组装出反 式钙钛矿太阳能电池，光电转化效率最高达到2．70％。 关键词：钙钛矿太阳电池，钌掺杂二氧化钛，锡锌氧多元氧化物，碘 化亚铜 万方数据 ABSTRACTSTUDY ABSTRACT STUDY oF THE ROLE OF ELECTRoN AND HOLE TRANSPORTING LAYER IN ORGANIC．INORGANIC HALIDE PEROVSKITE SOLAR CELLS ABSTRACT With the rapidly development of world economy and rapidly growth of population，it makes the demand for various resources increase day by day．But the stone energy as the coal，petroleum，natural gas increasingly dried up．It becomes the main reason of block the global economic development．The solar energy has widely distributed，clean and its renewable received widespread attention around the world．It is considered to be the most promising future energy source for the mankind． The solar cells based mainly on the principle of photovoltaic effect Can convert the sun’S rays directly into electricity．Accordingly,the fabrication of high-·performance and low--cost solar cells is the technological base of the wide utilization of the solar energy． The emergence of organic—inorganic halide perovskite solar cells has attracted great attention over the past few years．The perovskite solar cells have emerged as one of the most of promising candidates for the next generation of solar cells because of its high efficiency,low cost，and easy fabrication．The light absorbing semiconductor material had a perovskite polycrystalline structure，CH3NH3PbX3，where X i