捣固焦抗锌性能研究冶金工程专业论文.docxVIP

AbstractCoke，as Abstract Coke，as one of the most important materials m the blast furnace，functions as heating，reduction，and supporting stock column．The quality of coke is extremely important to blast furnace’S production．Due to the lack of high quality coal，Stamping technology is created．Stamping technology increase the blending ratio of high volatile coal or replace the bondability coal with weak bondability coal，which expand the source of raw materials and improve the quality of coke．In recent years，some enterprises began trying stamp charged coke instead of traditional top charged coke in blast furnace smelting．However，the Zinc load in some blast furnace is high，which influence blast furnace smooth operation especially the Zinc resistance of stamp charged coke is not sure at present，and the reaction process of stamp charged coke under high content of Zinc is short of deep research．In order to proving the effects of Zinc on thermal properties，reactivity and microstructure of stamp charged coke，this paper using thermodynamic and kinetic calculation to analyzing thermal reaction experiment，respectively using Optical Microscope，XRD and SEM to analyzing the experimental samples．The main contents and conclusions of this paper are induced as follows： (1)The influence of Zinc on stamp charged coke and top charged coke reactivity have been compared and analyzed at the experiment temperature of 900℃，1 000℃ and 1 1 00。C．The Zinc Resistance Properties of stamp charged coke is better than top charged coke at the same condition． (2)The coke solution loss reaction and the variation of Zinc compounds are analyzed by thermodynamic calculation，which found that the total pressure increase is not conducive to the solution loss reaction．The reaction order and activation energy has been studied by dynamics analysis according to the TG curves of the experiments， which pomted out that the reaction order of coke under high content of Zinc is 0，this mealls tllat the influence of Zinc in c