脂肪醇聚氧乙烯醚磷酸醋合成性能研究.doc

. 页 脂肪醇聚氧乙烯醚磷酸醋的合成与性能研究 摘要 本文对16-18碳脂肪醇4一聚氧乙烯醚磷酸酷(以下简称醇醚磷酸 酷)的合成及其性能进行了较为深入的研究。 醇醚磷酸酷是由脂肪醇聚氧乙烯醚和磷酞化剂反应制得，本文以 16-18碳脂肪醇4一聚氧乙烯醚和三氯氧磷为原料，对醇醚磷酸酷的合 成工艺进行了研究。首先，考察了反应物投料比，投料速度，投料温 度，反应温度，反应时间，水解加水量，水解温度，水解时间等因素 对产物组成，性能，颜色的影响，得到了合成具有一定单、双、三醋 含量的醇醚磷酸醋的方法。该反应的最佳反应条件为:醇醚与三氯氧 磷的投料比为2.7: 1，反应温度为1000C，反应时间为3h，投料时间 为60min,酷化反应过程中需通氮气保护;水解时加水量为水:三氯 氧磷=2: 1，水解温度为60 0C，水解时间为2小时，水解方式可以采 用水或30%的过氧化氢水解，用固体碳酸钾中和至PH=6-7;产品外 观为白色、蜡状固体，单、双、三酷含量分别为5. 45, 30%;反应 过程中不需要加入催化剂，产品适宜在洗化行业使用。其次，对在最 佳条件下合成的产品进行了各项理化性质和性能指标的检验:单、双、 三酷及游离磷酸含量，酸值，PH值，临界胶束浓度，克拉夫特温度， 熔点，表面张力，乳化力，发泡性，润湿力，分散力等。最后，对醇 醚磷酸mln--的应用进行了研究，进行了乳液性能检测，乳化力和稳定性 较好。 关键词:脂肪醇聚氧乙烯醚磷酸酷;三氯氧磷;单醋;双醋;三 醋;合成;理化性质;性能指标;应用; RESEARCH OF SYNTHESIS AND PERFORMANCE OF ALCOHOL POLYOXYETHYLENE ETHER PHOSPHATE ABSTRACT This paper is about the research of synthesis and performance of 16-18 carbon alcohol .4-polyoxyethylene ether phosphate (hereinafter referred to as alcohol polyoxyethylene ether phosphate). Alcohol polyoxyethylene ether phosphate is synthesized through the reaction between polyoxyethy fatty alcohol ether and phosphorylating agent.The synthesis technology of alcohol polyoxyethylene ether phosphate is studied here, 16-18 carbon alcohol 4-polyoxyethylene ether and phosphorus oxychloride used as the material. First, the observation is conducter to the reactants adding material ratio, adding material velocity, adding material temperature, reaction temperature, hydrolysis perdurability etc., which has effect on the formation, performance and color of the resultant, and results in the method of synthesizing alcohol polyoxyethylene ether phosphate with definite composition of mono-, di一and tri-ester. The optimum condition of reaction is as followed: The reactants adding ratio of polyoxyethy fatty alcohol ether and phosphorus oxychloride is 2.7:1，reaction temperature is 1000C，reaction perdurability is 3hrs, the reactants adding time is lhr, N2 is led to the reaction system while esterification reacting; the hydrolyzing water c