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- 2019-01-23 发布于福建
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Block 10
Stereo- and Regio-selectivity in
polymerizations as determined by
NMR: Tacticity etc.
Tacticity Introduction
• Vinyl polymers, i.e. polymers of
monomers H C=CHR ( R = Cl: PVC; R
2
= Me: PP; R= Ph: PS; R = COOMe:
PMA etc.) generate chiral centres
when they polymerize
• If a carbon atom has at least two
substituents the same, it is chemically B NOT B
not distinguishable from its mirror distinguishable
image.
•
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