东海大学化学工程与材料研究所.PDF

東海大學化學工程與材料研究所 博士論文 指導教授 :黃琦聰 博士 指導教授 :程學恆 博士 Design and Control of a Complete Azeotropic Distillation System Incorporating Stripping Columns for Isopropyl Alcohol Dehydration 研究生 :張文騰 撰 中華民國一○二年二月 Abstract Wen-Teng Chang Ph. D. of Department of Chemical and Material Engineering Because the reflux ratio used either in the pre-concentration column or the recovery column of the three-column heterogeneous distillation sequence for IPA dehydration system is quite small demonstrated by Arifin and Chien (2007), these two conventional distillation columns are both replaced by a stripping column in this study and a new separation scheme called Scheme 3 is thereby developed. The economic analysis of the proposed system shows it is more energy efficient and lower capital costs as compared to the two and three-column sequences afore-mentioned. Further, in developing a plant-wide control structure, a tray temperature control loop is implemented in each of the three columns which regulates reboiler duty in order to maintain the bottom product compositions for Scheme 3, and ratio control of the organic reflux flow to the feed flow rate of the azeotropic column is used to reject feed rate disturbance. Closed-loop responses to ±20% changes in fresh feed rate and feed H O composition show that the proposed strategy has good control performance. 2 This proposed scheme can be achieved three goals that are more energy saving, less total annual cost, and process easily controlled. I 謝致 首先感謝吾師 黃琦聰 博士，在專業知識上的傳授與待人處世啟 發 ，程學恆博士和謝樹木 博士在化材領域的諄諄教導，師恩沒齒