热耦蒸馏的热力学分析.pdf

华南师范大学学报 ( 自然科学版) 2004 年 11 月 JOURNAL OF SOUTH CHINA NORMAL UNIVERSITY 2004 年第 4 期 　　　　　　　　 Nov. 2004 　 　　　　　　　　 (NATURAL SCIENCE EDITION) 　No . 4 , 2004 : ( ) 文章编号 1000 - 5463 2004 04 - 0078 - 06 热耦蒸馏的热力学分析 吕向红1 ,2 , 陆恩锡1 ( 1. 华南理工大学化学工程研究所 , 广东广州 510640 ; 2 . 华南师范大学化学系 ,广东广州 510631) 摘要 :从热力学上分析了热耦蒸馏的节能原理 , 比较了有效能损失和热力学效率 ,并对液化天然气混 合物的分离分别按热耦蒸馏和常规蒸馏方案进行了严格模拟 ,结果表明 ,热耦蒸馏塔比常规蒸馏方 案节能约 21 % ,热力学效率也从常规方案的77 %提高到 118 %. 关键词 :热耦蒸馏 ; 蒸馏节能 ; 热力学效率 中图分类号 :TQ02831 　　　文献标识码 :A THERMODY NAMIC ANALYSIS OF FULLY THERMALLY COUPL ED D ISTILLATION LU Xiang - hong1 ,2 , LU En - xi1 ( 1. Chemical Engineering Research Institute , South China University of Technology Guangzhou 510640 , China ; 2 . Department of Chemistry , South China Normal University , Guangzhou 510631 , China) Abstract : Fully thermally coupled distillation was a type of complex distillation technique pro posed about 50 years ago and is thermodynamically more efficient than conventional distillation . In this paper , the energy - saving principles are discussed and thermodynamically analyzed . The separation of a liquefied natural gas mixture containing C4 - C6 + is rigorously simulated based on thermally coupled and conventional distillation schemes respectively . The results show that the thermally coupled configuration can save energy about 2 1 % and its thermodynamic efficiency is enhanced from 77 % to 118 % , as compared with conventional arrangements. Key words :fully thermally coupled distillation columns ; energy - saving di