蒸气压对聚合物包膜肥料氮素释放特性的影响.pdf

中国农学通报 2013,29(24):85-89 Chinese Agricultural Science Bulletin 蒸气压对聚合物包膜肥料氮素释放特性的影响 陈可可，张保林，侯翠红 （郑州大学化工与能源学院，郑州450002 ） 摘 要：为了从微观和动力学的角度揭示聚合物包膜肥料氮素释放的机理，研究了不同介质的蒸汽压对 国内外生产工艺、养分释放机理不相同的4 种聚合物包膜肥料中的氮素释放特性的影响。结果表明：在 水、KH PO 饱和溶液、KCl 饱和溶液3 种介质蒸汽压下，4 种供试肥料的氮素累积释放率均为：H O ＞ 2 4 2 KH PO 饱和溶液＞KCl 饱和溶液，利用一级动力学方程和Arrhenius 方程联合得出3 种介质蒸汽压下4 2 4 种供试肥料的氮素释放活化能依次为：H O ＜KH PO 饱和溶液＜KCl 饱和溶液。缓/控释肥料的氮素累 2 2 4 积释放率随包膜层内外的蒸汽压差增大而增大，包膜材料、肥料核心养分类型均影响肥料养分的释放。 关键词：蒸汽压；聚合物包膜肥料；氮素释放 中图分类号：S1 文献标志码：A 论文编号：2012-2201 Influence of Vapor Pressure on the Nitrogen Release of Polymer-coated Fertilizers Chen Keke, Zhang Baolin, Hou Cuihong (CollegeofChemicalEngineeringandEnergy,ZhengzhouUniversity, Zhengzhou 450002) Abstract: In order to reveal the mechanism of nitrogen release of polymer-coated fertilizers, the N release characteristic from 4 polymer-coated fertilizers which have different produce technics and nutrition release mechanism was investigated in this paper. The results showed that: based on the experiments of nitrogen release under different vapor pressure, the cumulate release rate of nitrogen from polymer-coated fertilizers was: H O saturated solution of KH PO saturated solution of KCl; the nitrogen release activation energy 2 2 4 from polymer-coated fertilizers was: H O saturated solution of KH PO saturated solution of KCl. The