过渡金属掺杂亚铁锌双金属氰化物催化合成生物柴油的.pdf

第40卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.40 No.2 2012年2月 Journal of Fuel Chemistry and Technology Feb. 2012 文章编号:0253鄄2409(2012)02鄄0197鄄05 过渡金属掺杂亚铁锌双金属氰化物催化合成生物柴油的研究 杨玲梅,吕鹏梅,罗摇 文,李惠文,王忠铭,袁振宏 (中国科学院广州能源研究所 中国科学院可再生能源与天然气水合物重点实验室,广东 广州摇 510640) 摘摇 要:研究了掺杂过渡金属盐(La、Ce、Zr、Mn)对亚铁锌双金属氰化物(DMC)固体酸催化剂合成生物柴油的影响,并采用 XRD、FT鄄IR、ICP、BET等方法对其进行结构和性能表征。 结果表明,1%的镧、铈、锆、锰金属盐对催化剂的活性都有提高,其 中,添加1%镧的DMC催化剂活性最高,在醇油摩尔比16颐1,反应温度160益,催化剂加入量2%条件下,反应7h,脂肪酸甲酯 收率达到99.3%。 过渡金属盐引入对催化剂的组成没有影响,但使得催化剂更加分散,颗粒粒径更小,比表面积变大,有利于 催化剂和反应物的接触,从而提高了催化剂活性。 关键词:过渡金属;双金属氰化物;生物柴油;固体酸 中图分类号:TQ032.4摇 摇 文献标识码:A Synthesis of biodiesel by transition metal doped Fe/ Zn double metal cyanide complex catalysts YANG Ling鄄mei,L譈 Peng鄄mei,LUO Wen,LI Hui鄄wen,WANG Zhong鄄ming,YUAN Zhen鄄hong (Key Laboratory of RenewableEnergy and Gas Hydrate,GuangzhouInstitute of Energy Conversion, ChineseAcademy of Sciences,Guangzhou摇 510640,China) Abstract:Effects of transition metals (La,Ce,Zr,Mn) on catalytic performance of double metal cyanide (DMC) catalysts for biodiesel synthesis were studied. The structure and performance of the catalysts were studiedusingXRD,FT鄄IR,ICP,BETetal. TheexperimentalresultsshowedthattheDMCcatalystpreparedby adding 1% of transition metal saltshad higher activity. The catalyst with highest catalytic activity was prepared by adding 1% ofLa(NO ) ·nH O. Under theconditionsofmethanol/ oilmolratioof 16颐1,catalystamount of 3 3 2 2% and temperature of 160益,a high yield (99.3%)of fatty acidmethyl esters (FAME)wasobtained within 7h. Theanalyticalresultsshowedthatadding 1% oftransitionmetalsdidnotchangethemolecularformulaofFe (II)鄄Zn double metal cyanide complex catalysts,while it improved particle dispersion,decreased particle size and increased surface area. Thiswast