金属基高发射率涂层耐热性及热震性能研究.pdf

第33 卷 第5 期 红 外 技 术 Vol.33 No.5 2011 年5 月 Infrared Technology May 2011 金属基高发射率涂层耐热性及热震性能研究 李泉灵，徐国跃，陈砚朋，徐飞凤，蒋 勇 （南京航空航天大学材料科学与技术学院，江苏 南京 210006 ） 摘要：以无机硅酸盐为粘合剂，过渡金属氧化物系列粉体为颜填料，制备出了金属基板上的高发射率 涂层，并对其耐温性及抗热震性能进行研究。通过 IR-2 型发射率测量仪器测试了涂层在 3～5 μm 波 段的发射率，并分别采用 XRD 和 SEM 表征了涂层的物相和微观形貌。结果表明：通过对颜填料的球 磨和表面改性，涂层可以耐受 1200℃高温，3～5 μm 波段的发射率在 0.9 以上，并且热震性能也有了 显著的提高，升温速度为 5℃/min ，固化温度为600℃，固化时间为2 h 时，抗热震性能达到了 10 次。 关键词：热震性；耐温性；高发射率；固化工艺 中图分类号：TN213 文献标识码：A 文章编号：1001-8891(2011)05-0284-05 Study of Thermal Endurance and Thermal Shock Resistance of High-emissivity Coating on Metal Substrate LI Quan-ling ，XU Guo-yue ，CHEN Yan-peng，XU Fei-feng ，JIANG Yong (Nanjing University of Aeronautics and Astronautics, College of Material Science Engineering, Nanjing 210006, China) Abstract ：High-emissivity coatings on metal substrate were prepared with silicate inorganic and transitional metal oxides series as adhesive and fillers, respectively. The thermal endurance and thermal shock resistance were investigated. The emissivity in 3～5 μm waveband of the coating was measured by IR-2. The structure and surface morphology of the coatings were characterized by X-ray (XRD) and scanning electron microscope (SEM). The results of experimental investigation indicated that the coatings were greatly improved in resistance to thermal shock which was attributed to the milling and surface modification of the fillers. And the emissivity in 3～5 μm of the coatings was increased to 0.9 and could bear temperature of 1200℃. With the warming rate, curing temperature and curing time of the coating was ste to 5℃/min, 600 ℃ and 2 h, respectively,