有机染料敏化太阳能电池的研发-eTop-工程科技推展平台.PDF

行 料 精 類 行 年年 行 參理 理 理 理 利 年 年 料 率力 率 料略 兩料 奈金 不 金 離料 料見 (phthalocyanine) (azo) (coumarin)料利 XRD SEM TiO 參數TiO 2 2 料 料 1 13 料 ( H-, C-NMR) 見 (UV-vis spectra) 料 Abstract Dye-sensitized solar cells (DSSCs) have been considered as one of the most promising solar cell technologies for their low cost and high efficiency comparable to that of silicon solar cells. The aim of this project is developing efficient and stable DSSCs. We focus on the development of the following two key materials: 1. the organic dyes do not contain noble metals; 2. high surface area nanocrystalline metal oxides electrodes. As organic dyes have narrow absorption spectrum profiles in the visible light region, we prepared the DSSCs consisting of mixed phthalocyanine and azo or coumarin dyes instead of single dye system to utilize the broad spectrum of sunlight. The crystalline phase and surface morphology of titanium oxide were characterized by using XRD, and SEM to investigate the effects of processing parameters on the films characteristic and microstructure. We have also synthesized the modified coumarin dyes as sensitizer of the DSSCs. The chemical structure of as synthesized modified coumarin dyes were characterized by the nuclear ma