石化废水深度处理及脱盐的中试研究.PDFVIP

中国环境科学 2009,29(9) ：929~934 China Environmental Science 石化废水深度处理及脱盐的中试研究 1* 1 2 1 1 2 陈洪斌 ,朱冠楠 ,张东宇 ,唐贤春 ,何群彪 ,丰德新 (1. 同济大学环境科学与工程学院,污染控制与资源化 研究国家重点实验室,上 200092 ；2. 中国石油华北石化公司,河北 任丘 062552) 摘要：针对石化行业污水回用处理设施很快失效的现状,开发了“集成式悬浮载体生物氧化－砂滤－臭氧活性炭处理－超滤反渗透” 的组合 工艺对炼油厂外排水进行深度处理.连续 7 个月的中试结果表明,处理后外排水中 COD、NH -N 、BOD 、油和浊度等均优于回用水标准, 3 5 可作为工业循环冷却水、绿化用水和办公等用水;常规深度处理的出水经过超滤反渗透处理后, 电导率稳定在 35~40µS/cm,可作为动力车间 的新鲜水,不会发生膜污染和堵塞问题.尽管外排水的水质波动很大,但是组合工艺运行稳定、可靠,具有突出的抗冲击性能. 关键词：含油废水；深度处理；脱盐；集成式悬浮载体生物氧化 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2009)09-0929-06 1* 1 Pilot study on oil refinery wastewater advanced treatment and desalination. CHEN Hong-bin , ZHU Guan-nan , 2 1 1 2 ZHANG Dong-yu , TANG Xian-chun , HE Qun-biao , FENG De-xin (1.State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China ； 2.Huabei Petrochemical Company, China National Petroleum Corporation, Renqiu 062552, China). China Environmental Science, 2009,29(9)：929~934 Abstract ：As oil refinery wastewater advanced treatment devices gradually lost their function one or two years after operated in some petrochemical companies, a combined advanced treating process of “integrated suspended carrier biological oxidation, sand filtration, ozone-biological activated carbon filtration”and desalination process of “ultrafiltration and reverse osmosis (UF+RO)” were developed. Seven-month pilot-test showed that m