金属酞菁及其衍生物的制备和光学性能-高分子化学与物理专业论文.docxVIP

金属酞菁及其衍生物的制备和光学性能 金属酞菁及其衍生物的制备和光学性能 摘要 摘要 金属酞菁是一类非常重要的三阶非线性光学材料。本论文合成并测试了以下三类共 29种酞菁化合物的光学性能。 (1)合成了以铝、铁、钴、镍、铜等不同金属为中心原子的金属酞菁，并用红外光 谱、元素分析表征了结构，用四波混频方法测定了三阶非线性光学极化系数以 及响应时间，系统地研究了中心原子对酞菁化合物的三阶非线性光学性能的影 响。 (2)合成了以卤素、羧基、硝基、氨基等不同电子效应的官能团为取代基的酞菁化 合物，并用红外光谱、元素分析表征了结构，用四波混频方法测定了三阶非线性 光学极化系数以及响应时间，系统地研究了取代基的电子效应对酞菁化合物三 阶非线性光学性能的影响。 (3)利用四羧甲基酞菁铜和氯化亚砜反应生成四酰氯酞菁铜后，与脂肪醇、脂肪胺 以及不同电子效应的芳胺反应，得到了一系列脂肪链取代基或芳烃取代基的酞 菁铜衍生物，并用红外、元素分析、核磁共振氢谱等方法对这些衍生物进行了 结构和取代度的表征，并测定了它们在溶液中的荧光性能。由于这些取代基的 引入，极大地提高了酞菁化合物在有机溶剂中的溶解性能。 关键词：酞菁化合物，三阶非线性光学，荧光，溶解性 作 者：姚社春 指导老师：路建美 金属酞菁及其衍生物的制备和光学性能 金属酞菁及其衍生物的制备和光学性能 摘要 Abstract Metal—phthalocyanine(Mt—Pc)is a important kind of third·order nonlinear optical(NLO) material．This paper reports the synthesis of a series of metal—phthalocyanine as the following： (1)The phthalocyanine with different central metal such as A1，Fe，Co，Ni and Cu．Their structures were verified by IR,UV-Vis and elemental analysis．The third—order non-linear optical coefficient∥’and the response time of these products were measured by degenerated four-wave mixing(DFV泖vf)technique．The effect on the property of tlliId—order NLO by cen仃al metals was studied． (2)The phthalocyanine substituted by different group such as halogen，carboxymethyl， nitro．amino．Their structures were verified by IR，Uv-Vis and elemental analysis．The third．order non—linear optical coefficient∥’and the response time of these products were measured by degenerated four-wave mixing(DFWM)technique．The effect on the property ofthird—order NLO by central metals an substituting groups was studied． (3)After reacting the aliphatic alcohol，aliphatic amine and aromatic amine with tetra-formyl chloride copper phthalocyanine， which obtained by reacting tetm-carboxymethyl copper phthalocyanine with thionyl chloride，a series of copper phthalocyanine derivatives substituted by aliphatic chain and areno were obtained．IR， UV-Vis，elemental analysis and 1H-NMR