堇青石玻璃陶瓷的研制-材料学专业论文.docx

AbstractMgO—A1203～Si02 Abstract MgO—A1203～Si02 cordierite glass—ceramics were prepared by sintering method in this paper．In order to decrease the COSt of the product，the industrial raw materials alumina、talcum、kaolin were used to replace the high pure A1203、 MgOandSiOzin this research．and some力02 was also added to improve the performance． The crystallization ofthe stoichiomemc cordierite was studied by using TG- DTA and XRD．The results showed that stoichiometric cordierite glass powder could nucleate and crystallize by means of the surface of the powder．The pv2mary phase of sample was i_I-cordierite and the final phase was a-eordierite． These revealed that it’S possible to prepare the cordierite glass—ceramics using the industrial raw materials．However,it’S difficult to sinter the stoiclliomemc cordierite．In order to improve the sintering character,it’S indispensable to change the composition ofthe basic glass． The optimal content of 7i02 was studied by the test of performances and microstructure of samples．The results showed that the properties were of the optimum when adding 5％乃02 in glass—ceramics． The optimal processing parameters of the non·stoichiometric cordierite glass-ceramics were also studied by the test ofperformances and microstrcture of samples．The results proved that the optimal nucleation temperature is 780(2， nucleation time 2h，crystallization time 2h，and heating rate 3(2／min． The crystallization of the non—stoichiometric cordierite WaS studied by XRD． The results showed that the first phase of sample is p-cordierite and the fmal phases are ct—cordierite，forsterite，MAT and rutile． The change of group in cordierite samples were studied by FIIR．The results showed that only the change of Silicon-oxygen chain was detected in the samples without T／02一Quadridentate Titanium哪detected in the samples with 5％ nD2 at the low temperature．However，absorption peak of sexadentate Titanium Was not detected at the high temperature，it might not be detected by IR Spect