中国红豆杉中主要紫杉烷类物质的分布研究-林产化学与工业.PDFVIP

25 1 Vo.l 25No. 1 2005 3 Chem istry and Industry of ForestProducts M ar. 2005 * * 赵春芳, 余龙江 , 刘 智, 孙友平, 李文兵 (华中科技大学生命科学与技术学院, 湖北 武汉 430074) : 对中国 豆杉[Taxus ch inensis( Pilg. )Rehd. ] 中的紫杉烷类化合物紫杉醇及两种重 要前体巴卡亭 III( B III)和 10-脱乙酰巴卡亭 III( 10-DAB)的分布进行了研究结果表明,紫 杉醇的含量在同一棵树中的分布依主干皮根皮侧枝树皮种子须根嫩枝叶的次序递减, Z AO C F 并发现侧枝茎中紫杉醇在横截面方向呈梯度分布, 且紫杉醇含量最高部位是在次生木质层 10-DAB和 B III在叶中含量最高,在须根中含量最低,叶子中 10- DAB的含量达 0. 02% ~ 0. 03%, 高于 B III 的含量在 2~ 3 a生的小树枝叶中未检测到紫杉烷类物质, 提示其合成可能与植株发育有关紫杉醇在 30 a树龄的当年生嫩叶中春季高于秋季,而 10- DAB在当年生和多年生的叶中积累都较多, 且秋季比春季含 量高 : 中国 豆杉; 紫杉烷; 紫杉醇 : TQ351. 014; Q949. 661 : A : 0253- 2417( 2005) 01- 0089- 05 DISTRIBUTION OF TAXOL AND TAXANES IN YEW TREE Z AO Chunfang, YU Longjiang, LIU Zhi, SUN Youping, LIW enbing (Schoo l of L if e Sc ience and T echnology, H uazhong Un iv ersity of Sc ience and T echnology, W uhan 430074, Ch ina) A bstrac t: The contents of taxol and its wt o mi portant precursors, namely baccatin III( B III) and 10deacetylbaccatin III ( 10DAB) in various tissues of yew trees [Tax us ch inensis ( Pilg. )Rehd. ] at different ages in different seasons were quantified by PLC. The results indicated that the content of taxol decreased successively according to stem barks, root barks, lateral stem barks, seeds, fibres, twigs and young needles in a single tree. The gradientdistribution of taxol concentration along radialdirection of cross section of lateral stem was surveyed for the first tmi e. It was foun