毕业改进的mcallister三体模型用于推算二元混合物的黏度.docx

改进的McAllister三体模型用于推算二 元混合物的黏度 摘要：McAllister三体模型被普遍认为是针对液体二元混合物运动黏度的最佳关联式。木文对 McAllister三体模型进行了研究，在对三类(醇类/醇类、烷坯/醉类、烷坯/烷坯)二元混合物的黏度 数据进行文献搜集和整理的基础上，发现模型中的相互作用参数(旳2和”21)随二元混合物的等效分 子量和温度呈现出规律性的变化。因此，木文建立了一种改进的McAllister三体模型，并对乙醇与丙 醇、丁醇、戊醉、己醇、庚酵、辛醇、壬醉、癸醉体系，异辛烷与丙醇、己醉、戊醇、辛醇体系， 正丁基环己烷与庚烷、辛烷、壬烷、癸烷、十二烷、十四烷体系的黏度进行了推算，计算结果表明， 计算值与实验值的总体平均绝对偏差为1.00%,最大偏差为9.75%。 关键词：McAllister三体模型；乙醇+醇类；正丁基环己烷+烷坯类；异辛烷+醇类 Improved McAllister Three-Body Model to Calculate Viscositiesof Binary Mixtures WANG Xiao-jie, LANG Han-xiao, MA Qian, WANG Xiao-po (Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xian Jiaotong University, Xian, Shanxi 710049, China) Abstract McAllister three-body model is generally regarded as the best correlation for the kinematic viscosities of binary liquid systems? In this work, McAllister three-body model was proposed based on the viscosity data of three types of binary mixtures (alcohols/alcohols, alkanes/alkanes, alkanes/alcohols). We found that the model interaction parameters (v12 and v2i) exhibit regular trends along with equivalent molecular weights of binary mixtures and temperatures? Therefore, an improved McAllister three-body model was proposed? The new model was used to calculate the viscosities of different binary mixtures, including ethanol + 1-propanol, + 1-butanol, + 1-pentanol, + 1-hexanol, + 1-heptanol, + 1-octanol, + 1-nonanol, and + 1 -decanol systems, //-butylcyclohexane + 1 -heptane, + 1 -octane, + 1-nonane, + 1 -decane, + 1 -dodecane, and + 1 -tetradecane systems, and 2,2,4-Trimethylpentane+1 -propanol, +1-pentanol, + 1-hexanol, and +1-heptanol systems? The results show that the overall average absolute deviation is 1.00% between the calculated data and experimental values, and the maximum deviation is 9.75%? Keywords McAllister thrcc-body model; ethanol/1 -alcohols; n-butylcyclohcxanc/1 -alkanes; 基金项目：国家自然科学基金资助项D (No. 2,24-trimeihylpentane /I -alcohols o.引言 黏度是用于描述流体流动阻力的一种基本属性，液体混合物的黏度对于流动系统 的研究尤为重要，比如原油开采