原位复合技术和原位复合材料讲义-2011年.pptVIP

α-Al2O3： 500nm α-Al2O3：200nm、 α-Al2O3： 200nm α-Al2O3： 500nm Materials Design of Nanocomposite Ceramics High strength and reliability, Excellent H. T. mechanical properties, Toughness (?) Nano-dispersion Intra-type Inter-type Intra/Inter-type Nano/Nano-type New functions Machinability Superplasticity Micro-sized particle, whisker or fibers Micro/Nano Hybrid-type Mutual Nano-type Phase A Phase B Super tough and strong (at room and high 　　　　　　　　　 temperatures) (A/B + B/A) High Resolution TEM Image of Si3N4/SiC Nanocomposite 　Prepared from Amorphous Si-C-N Powder New Functions : Superplasticity Superplastic deformation for Si3N4/SiC Nanocomposites F. Wakai, Y. Kodama, S. Sakaguchi, N. Murayama, K. Izaki, K. Niihara, Nature, 344, 421-3(1990) High Resolution TEM Picture of Al2O3/SiC Nanocomposite Al2O3/5vol%-SiC Nano Com. Al2O3 monolith Typical Microstructure Intragranular SiC Dispersions ISIR Osaka Univ. of Al2O3 Ceramics Mechanical Property Improvement by Nanocomposite Technology 1) Fracture mode Trans/Inter to complete transgranular (up to 1300 to 1400 ℃ ) 2) Fracture toughness Little improvement (No decrease compared with monolithic materials) An in-grain toughening 3) Abrasive and cutting performance Great improvement 4) Fracture strength 2 to 5 times improvement 5) Maximum operating temperature above which strength starts to decrease 200 to 700 ℃ improvement 6) Creep resistance 3 to 4 times improvement 7) Others (Microcomposite): 15-25vol% (Nanocomposite): 3-5vol% (50-100nm) : 0.1vol% (10nm) Mechanism: Highly localized stress/strong interface bonding Approach to Multi-Functional Materials-- Through Nanocomposite Concept -- Strengthening by Pores Young’s Modulus 　Si3N4: 380 MPa BN : 40 MPa Fracture Strength Si3N4: 800-1800 MPa BN:100 MPa (Si3N4 , SiC, AlN, Al2O3) – BN Systems Various Kinds of Mult