高真空多层绝热低温储罐中含PdO的吸气剂在77K下吸附性能的研究.PDF

　　　　　　　　 34 　2 　　　　　　　　　　　　 　　　　　　 106 CHINESE JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY 2014 2 　 PdO 77 K 1, 2 ＊ 1 3 2 2 陈树军 　付　越 　刘宏波 　谭　粤 　夏　莉 (1.()　　266580;2.　　510655; 3.　　065000) Adsorption of PdO-Containing Getter at 77 K in High Vacuum Multilayer Insulation Cryogenic Vessels 1, 2 ＊ 1 3 2 2 Chen Shujun , Fu Yue , Liu Hongbo , Tan Yue ,Xia Li (1.College of Pipeline and Civil Engineering, China University of Petroleum(East China), Qingdao 266580, China; 2.Guangdong Institute of Special Equipment Inspection, Guangzhou 510655, China; 3.China Petro Leum Pipeline Engineering Corporation, Langfang 065000, China) 　　Abstract 　The adso ption of the PdO-containing gette at 77 K, in high vacuum insulation c yogenic vessel was mod- eled, based on B unaue -Emmett-Telle (BET)s isothe m and statistic the modynamics.The adso ption isothe m model is valid unde the conditions:the adjacent laye s have identical chemical potential, the gas-phase adso ption potential equals to the laye s chemical potential in adso bed phase, and the gas phase has the same adso ption potential as the liquid phase in gas-liquid equilib ium .The adso ption of the PdO-containing gette at 77 K was measu ed .The satu ated adso p- tion capacity of one monolaye , adso ption constant, and adso ption laye s we e calculated and expe imentallymeasu ed. Since Keesom potential function desc ibes the inte action of gas molecules, theadso ption isothe m equation could be solved.The esults show that N2 was physiso bed to the PdO-containi