乌氏黏度计铜氨溶液法测定棉纤维的聚合度_陈守清.pdf

24 3 Vol. 24No. 3 79 2015 5 CHEMICAL ANALYSIS AND METERAGE May 2015 doi 10.3969j.issn.1008–6145.2015.03.022 1 2 (1. 122000 2. 122400) 1 000 0.751.0 gL 1 000 1.5 gL 0.5 molL 1 molL NH4+ n 3%( =4) O656 A 1008–6145(2015)03–0079–04 Determination of Polymerization Degrees of Cotton Fiber by Using Ubbelohde Viscometer–Copper Ammonia Solution Method 1 2 Chen Shouqing Tian Yueyun (1. Chaoyang Institute of Products Quality Supervision and Inspection Chaoyang122000 China 2. Jianping Huiying Chemical Industry Co. Ltd. Jianping122400 China) AbstractThe method for determination of polymerization degree of cotton fi ber by using copper ammonia solution Ubbelohde viscometer was established. When the polymerization degree of cellulose was more than 1 000 cellulose concentration in copper ammonia solution was 0.75–1.0 gL when the polymerization degree was below 1 000the cellulose concentration was 1.5 gL. With cotton fi ber balance sample preparation cellulose copper ammonia solution, copper ammonia solution was joined into 0.5 molL sulfuric acid standard solution, the excess sulfuric acid was titrated by using 1 molL sodium hydroxide standard solution with methyl orange as the indicator, the concentration of NH4+ in copper ammonia solution was determined, then the average degree of polymerization was calculated. The relative standard n deviation of determination results was less than 3%( =4). The method is fast with