稳定苯乙烯丙烯酸丁酯细乳液的制备-中国科技论文在线.PDFVIP

中国科技论文在线 / * 谭必恩 ( 100095 ) 张廉正 ( 100076 ) 胡 芳 张洪涛 李建宗 ( 430062 ) 以十二烷基硫酸钠( SDS) 作乳化剂, 不同链长的脂肪烃或脂肪醇作共乳化剂, 分别用搅拌和超 声乳化方法制备一系列苯乙烯( St) / 丙烯酸丁酯( BA) 细乳液测定细乳液稳定性的结果表明, SDS/ 十六烷 (HDE) 的乳化效果最佳,HDE 先与单体混合结合超声波制备的细乳液最稳定乳化剂共乳化剂的种类和浓 度乳化温度超声时间等对细乳液的稳定性均有影响 细乳液, 稳定性, 均质化, 制备 Preparation of Stable St/ BA Miniemulsion Tan Bien ( Beijing Institute of Aeronautic Materials Beijing 100095 ) Zhang Lianzheng ( Aerospace Research Institute of Materials and Processing Technology Beijing 100076 ) Hu Fang Zhang Hongtao Li Jianzong ( Chemistry and Materia lCo ege, Hubei University Wuhan 430062 ) Abstract Using SDS as surfactant and fatty alcoho lor alkane with long chain as cosurfactant, a series of St/ BA miniemulsion were prepared by stirring and ultrasonification. The experimenta lresults showed that SDS/HDE is the best surfactant combination. If the previously prepared mixture of HDE and monomers was added to the surfactant solution, the more stable miniemulsion could be obtained. Ultrasonification was better than highspeed stirring. The surfactant and surfactant concentration, the emulsification temperature and the time, etc, would influence the stability of miniemulsion. Keywords Miniemulsion preparation, Emulsion stability, Monomer droplet,Ultrasonification 1 ( submicron) [ 1] , ( miniemulsion) , 70 , Lehigh