微波辐射下松香与乙醇的快速酯化反应-林产化学与工业.PDFVIP

22 2 Vol. 22 No. 2 2002 6 Chemistry and Industry of Forest Products June 2002 * 林中祥 ( 南京林业大学 化学工程学院, 江苏 南京 210037) LIN Z X : , ,24 min, 3. 88 mgKOH/g12%~ 16%, 2~ 3 , : ; ; :T 351. 471 : A 2002 ,, , ,, , , , , [ 1] 72 h 8 mgKOH/ g , 60%, , , , [ 2] [3~ 7] , , , , 24 min 4.0 mgKOH/ g , 1 ,;FR1, 70 mL, 1.2 MPa ,; 23 L , 700 W;, , , , , , GB 10287- 88 :2001- 08- 30 :( :( 1957- ) , , , , , Email: lin602@ * 2001 90 22 , , , ,, ,, , ,, , , , ,, , 2 2. 1 , 3. 0 g9. 0 g0. 5 g700 W 24 min , , , 1 ~ 4 1 2 Fig. 1 Effect of reaction time on acid value Fig.2 Effect of microwave power on acid value 3 4 Fig.3 Effect of catalyst amount on acid value Fig. 4 Effect of ethanol amount on acid value 1~ 4 ,, , , 700 W , , , ,12 min , 10 mgKOH/ g,24 min , 3.88 mgKOH/ g, 3~ 4 , 12%~ 16% ,2~ 3 , , , ,, 2.2 2 : 91 ,, , 1 1 , 25 h , 1 107.5 mgKOH/ g, Table 1 Effect of reflux time on acid value of products - 1 , / h / ( mgKOHg ) reaction time acid value ,