冰水结构和反常物性-科学网.PDF

冰水结构和反常物性 1 2,* 3 1 3 1,4,* 姚闯 张希 黄勇力 李蕾 马增胜 孙长庆 1． 重庆市超常配位键工程与先进材料技术重点实验室，长江师范学院，重庆408100 2． 深圳大学纳米表面科学与工程研究所，深圳 518060 3． 湘潭大学材料科学与工程学院，湘潭411105 4． 南洋理工大学电气与电子工程学院，新加坡639798 Contents 1.  引言：机遇与挑战  3  2.  对策：思维的转变  6  3.  原理：禁戒与守恒  7  3.1.  质子—孤对数目与氢键的构型守恒  7  3.2.  分子取向规则与质子隧穿能量禁戒  7  3.3.  氢键作用势与水的强涨落单晶结构  9  3.4.  氢键受激协同弛豫与水的反常物性  10  4.  方法: 谱学与解析  11  5.  进展: 谜题的探解  12  5.1.  温驱密度震荡：冷膨胀准固态与浮冰机理  12  5.2.  低配位超固态：冰皮润滑与水表皮超疏水  14  5.3.  压致氢键对称：准固态相边界拓展与复冰  15  5.4.  热水速冷之谜：氢键记忆与水表皮超固态  18  6.  结论：启示与展望  19  Contents 1. Introduction: Challenges and Opputinities Error! Bookmark not defined. 2. Stratigies: Manner of Thinking Error! Bookmark not defined. 3. Principles: Rules of Conservation and Prohibition .. Error! Bookmark not defined. 3.1. 2N Number and O:H-O bond Configuration Conservation Error! Bookmark not defined. 3.2. Molecular Orientation and Proton Tunneling Prohibition .. Error! Bookmark not defined. 3.3. Water Single Crystal and O:H-O Bond Potential Path Error! Bookmark not defined. 3.4. O:H-O Bond Coorpertivity and Ice Water Anomalies Error! Bookmark not defined. 4. Method: Spectrometrics and Analysis Error! Bookmark not defined. 5. Progress: Mysteries Resolution Error! Bookmark not defined. 1    5.1. Quasisolid Cooling Expansion: Ice Floating and Density Osc illation ... Error! Bookmark not defined. 5.2. Undercoordination Supersolidity: Slipperiness and Skin Hydorphobicity Error! Bookmark not defined. 5.3. O:H-O Symmetrization: Quasisolid Phase Boundary Dispersion and Regelation Error! Bookmark not defined. 5.4. Hot Water Cools Faster: O:H-O Bond Memory and Skin Super