低维结构铁电材料光电性能和铁电薄膜红外焦平面列阵器件物理研究_英文_.docVIP

第 20 卷 第 2 期2003 年 6 月中 国 第 20 卷 第 2 期 2003 年 6 月 中 国 科 学 院 研 究 生 院 学 报 Journal of the Graduate School of the Chinese Academy of Sciences Vol . 20 No . 2 J une 2003 EXCERPT OF DISSERTATION Optical and Electrical Properties of Lo w2Dimensional Ferroelectric Materials and Device Physics of Ferroelectric Thin Film Infrared Focal Plane Arrays 3 CHU J un2Hao TAN G Ding2Yuan YU J ian ( S hanghai Institute of Technical Physics , Chinese Academy of Scienses ,S hanghai 200083 ,China) ( Received 4 December 2002) Abstract First , the grain size effect on ferroelectricity , phase transformation , lattice dynamics , and pho2 toluminescence properties of nanocrystalline BaTiO3 were studied. Second , the orientation mechanism , op2 tical and electrical properties of highly oriented lead zirconate titanate thin film heterostructures prepared by chemical solution methods were studied. Third , the factors determining the performance of monolithic ferro2 electric thin film infrared focal plane arrays were investigated using a modeling method. Key words nanocrystalline BaTiO3 , grain size effect , phase transformation , oriented ferroelectric thin film heterostructures , distributed parameter model of ferroelectric film infrared microsensor CL C O73 Infrared detectors have numerous applications ranging from thermal imaging to surveillance . Currently , detectors are generally based on a reversed2biased junction comprising a narrow band gap semiconductor that separates and de2 tects the photogenerated charge created by an absorbed IR photon. For high sensitivity , these materials must be main2 tained at low temperatures , and thus refrigeration hardware is needed. As an alternative way , those temperature2sen2 sitive materials that do not require cooling are being developed for infrared detection , among which ferroelectric mate2 rials are promising candidates as sensitive and cheaper thermal detectors. Compared with the bulk case , the properties of ferroelect