利用铁矿尾矿制备轻质隔热保温墙体材料研究分析.docVIP

个人收集整理 仅供参考学习 个人收集整理 仅供参考学习 PAGE / NUMPAGES 个人收集整理 仅供参考学习 利用铁矿尾矿制备轻质隔热保温墙体材料地研究 专 业：矿物加工工程 硕 士 生：袁蝴蝶 指导教师：尹洪峰 教授 摘要 本文以梅山铁尾矿为原料，机械起泡工艺结合水基凝胶注模成型工艺制备了轻质隔热保温墙体材料.研究了pH值、分散剂地含量、固相含量、以及尾矿粒度对浆料流变性能地影响；研究了发泡剂与发泡剂地添加量对浆料发泡性能地影响、料浆地胶凝化特性和坯体地干燥工艺制度；研究了粘土水泥结合相制备轻质隔热保温墙体材料地制备工艺和性能.实验研究结果如下：b5E2RGbCAP 第一部分：凝胶注模工艺制备轻质隔热墙体材料 (1) 浆料中固相含量为55vol.%，分散剂为0.25wt.%时，在pH=6.00地情况下，可获得高固相含量流变性能良好地悬浮液.p1EanqFDPw (2) 十二烷基苯磺酸钠、十二烷基磺酸钠和液态皂地添加量分别为0.8 wt. %、0. 8wt.%、0.4-0.5wt.%时浆料地发泡性能最好；催化剂、引发剂添加量分别为0.13 wt. %、0.45wt.%时，在60min左右凝胶化反应相对完全.DXDiTa9E3d (3) 低温高湿与高温低湿结合干燥方式可获得不开裂、强度高地坯体，缩短了干燥周期.但此工艺难以控制，难于工业化生产.RTCrpUDGiT 第二部分：粘土水泥结合相制备轻质隔热墙体材料 (1)在pH值9.4时，随着pH值地增大浆料地粘度是减小地，但当pH值9.4时，随着pH值地增大浆料地粘度是增加地.pH值=9.4时浆料地粘度最低.5PCzVD7HxA (2)比较三种发泡剂（十二烷基磺酸钠、十二烷基苯磺酸钠、液态皂）以及各自地加入量，发现：以液态皂为发泡剂，且当加入量为0.5%时发泡性能较好.jLBHrnAILg (3)材料地体积密度为1.12g/cm3，耐压强度为18.3MPa，导热系数0.37 W/(m·K)气孔率为65%，且气孔较规则，分布较均匀，因此该材料接近轻质隔热墙体材料地要求.xHAQX74J0X 关键词：尾矿；凝胶注模；发泡剂；轻质隔热；墙体材料 Study on the Preparation of light heat-insulation wall materialLDAYtRyKfE with iron tailings Specialty:Mineral process engineering Candidate：YuanHudie Advisor:Pro. Yin Hongfeng Abstract Light heat-insulation wall material was prepared using the meishan iron tailingsas raw material and combining mechanical foaming process and water-based gel-castingmethod. Effects of the pH value,dispersant content, solid-phase content, as well as the size of the tailings on the rheological properties of slurry were investigated.?Effect of foaming agent and the content ofthem on the slurry were also investigated,meanwhile, gelatination performance and drying schedule of body were researched. The preparation process and properties of light heat-insulation wall material combined by clay and cement were investigated.Theresultswere as follows:Zzz6ZB2Ltk Part one:Gelcasting processto prepare lightweight thermal insulation wall materialsdvzfvkwMI1 (1) Suspension with high solid content and good rheological property can be prepared, when the solid content in slurry was 55vol%, the dispersio