新型有机-无机杂化钙钛矿发光材料的研究进展.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 1894 Acta Phys. -Chim. Sin. 2016, 32 (8), 1894－1912 August [Review] doi: 10.3866/PKU.WHXB201605034 新型有机-无机杂化钙钛矿发光材料的研究进展 肖 娟 张浩力* (兰州大学功能有机分子化学国家重点实验室，化学化工学院，兰州730000) 摘要：作为近几年来光伏领域最具竞争力的材料之一，有机-无机杂化钙钛矿受到了广泛的重视。除了在光 伏领域的潜在应用，钙钛矿材料也显示出了独特的光致发光与电致发光特性。本综述回顾了近期有机-无机 杂化钙钛矿材料的快速发展历程，详细介绍了其在发光领域的研究进展与应用前景；概括了钙钛矿发光材料 的特性及影响因素、发光原理、光谱可调节性，重点介绍了形貌对钙钛矿发光性能的影响；进而探讨了钙钛 矿材料在发光二极管、激光器件以及发光场效应晶体管领域最新的应用进展。最后，展望了钙钛矿材料的关 键性热点问题以及所面临的挑战，并尝试给未来钙钛矿材料的商业化途径指出方向。 关键词：钙钛矿；形貌；光谱可调；发光二极管；激光；发光场效应晶体管 中图分类号：O649 Recent Progress in Organic-Inorganic Hybrid Perovskite Materials for Luminescence Applications XIAO Juan ZHANG Hao-Li* (State Key Laboratory of Applied Organic Chemistry, College of Chemistry Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China) Abstract: As one of the most promising materials in the field of photovoltaics, organic-inorganic hybrid perovskites have attracted widespread attention in recent years. In addition to their promising applications in the field of photovoltaics, perovskite materials also exhibit outstanding photoluminescence and electroluminescence properties. This paper reviews the latest developments in organic- inorganic hybrid perovskite materials, with particular attention paid to the luminescence. Firstly, a summary of the fundamental issues related to the unique light emitting characteristics and influencing factors of perovskite materials is provided, including the light-emitting mechanism and principles r