酚大环内酯和聚醚类兼容模式.PDF

Biosynthesis of natural pprroduoducctsts Phenol, MACROLIDES大环内酯 AND POLYETHERS 了解酚类、大环内酯类和聚醚类化合物的结 构特点、生物合成途径和生物活性。 THE ACETATE PATHWAY: FATTY ACIDS AND POLYKETIDES （多酮） Polyketides constitute a large class of natural products grouped together on purely biosynthetic grounds. Their diverse structures can be explained as being derived from poly- -keto chains, formed by coupling of acetic acid (C2) units via condensation reactions, ii..ee.. nnCHCH33CCO2O2HH −−−−−−→−→−[[CHCH22CCO]O]nn−− The formation of the po