聚苯胺微管表面化学镀镍与电磁特性研究ElectrolessPlatingofNickel.PDF

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第2 期, 163～168 ACTA CHIMICA SINICA No. 2, 163～168 ·研究论文· 聚苯胺微管表面化学镀镍与电磁特性研究 刘建华* 周新楣 李松梅 (北京航天航空大学材料科学与工程学院 北京 100083) 摘要 采用原位掺杂的方法合成了聚苯胺微管, 使用化学镀方法制备聚苯胺微管/Ni 复合材料, 运用 X 射线粉末衍射 (XRD)和能量色散光谱(EDS)研究了聚苯胺微管化学镀镍前后的微观结构; 利用UV-VIS 吸收光谱研究了聚苯胺微管表 面镀镍过程中SnCl2 敏化、PdCl2 活化以及镀液温度对聚苯胺微管主链结构的影响; 采用波导法研究了聚苯胺微管化学 镀镍前后在8.2～12.4 GHz 频段内的电磁参数. 研究发现: 聚苯胺微管表面均匀地沉积了一层紧密Ni 镀层, Ni 介于晶态 和非晶态之间, 并有少量Ni3P; SnCl2 敏化、PdCl2 活化过程对聚苯胺主链影响不大, 施镀温度对聚苯胺微管主链结构影 响很大, 35 ℃时, 主链结构变化最小, 随着温度的增高, 聚苯胺还原程度变大. 关键词 导电聚苯胺微管; 化学镀; UV-VIS; 复合材料 Electroless Plating of Nickel on the Surface of Polyaniline Microtubules and Electromagnetic Property Study LIU, Jian-Hua* ZHOU, Xin-Mei LI, Song-Mei (School of Materials and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083) Abstract Polyaniline microtubules were prepared by using in situ doping method and polyaniline micro- tubule/Ni composites by electroless plating method. The sample before and after coating was checked via X-ray diffraction and energy dispersive spectrometry. The effect on polyaniline microtubule fundamental chain in the process of electroless nickel plating included catalysis by SnCl , activation by PdCl and tem- 2 2 perature of electroless plating solution. The electromagnetic property was studied to find that Ni has been deposited on the surface of polyaniline microtubules orderly and tightly, the process of cataly