硅基太阳能电池表面减反射结构的制备与表征材料物理与化学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 II II Abstract With the growing shortage of traditional fossil energy sources and the serious damage to the ecological environment, it is an urgent need for an environmentally friendly clean and renewable energy. The solar cells convert light directly into electrical energy, without pollution for environment, whose R D is important, which can improve the ecological environment and promote the development of low-carbon economy. Therefore, in this paper, we design and prepare the antireflective structure in the surface of silicon solar cells to reduce efficiency losses , to provide a basis of the new generation of highly efficient solar cells. We carry out the study of new micro-nano structure in the silicon surface , using the metal-sesisted chemical etching method to design and preparenanostructure. On the basis of understanding fully the catalytic mechanism of precious metal particles and anti-reflection mechanism of silicon surface nanostructure. Firstly , silver nano- particles are deposited on the silicon surface by ion sputtering and silver mirror reaction , and then use their catalytic properties to achieve the acid etching of silicon; we also adopted single-step whole solution method to directly implement the acid etching of silicon. As a result, we obtain different kind of nanostructures - porous structure, nano-cluster structure and the nanowire. Finally, we measure the reflectance spectra of these nanostructure. On the one hand, we investgate different deposition conditions which have effect on the morphology of silver nanoparticles and its distribution, master the controlled deposition process of silver nanoparticles on the silicon surface; the other hand, using the catalyst of nanosilver particles , we obtain the effect of these parameters on the surface morphology by changing the morphology of silver nanoparticles, the composition of acid etching solution and etching time,et al, parameters to realize the etching of sil