贵州松桃道坨锰矿地球化学特征-矿物学·岩石学·矿床学专业论文.docxVIP

万方数据 万方数据 摘 要 新元古界南华系大塘坡组黑色页岩是我国重要的含锰地层，2010 年在该含 锰层位中发现的贵州道坨锰矿已成为我国最大的锰矿床。本文通过对道坨锰矿含 锰岩系主量、微量元素分析，离子探针分析，锰矿石中碳酸锰的提取分析以及 Re-Os 同位素分析，探讨锰矿的形成环境、形成过程、形成年代及物质来源，初 步得出如下结论： 1、锰矿石的 Al/Ti 比值说明锰 Mn 主要是在离陆源较远的深度较大的水体中 形成的；Fe/Mn 比值说明锰 Mn 是在适度的氧化还原条件下形成的。 2、微量元素中 Co、Mo 元素富集以及 Th/U、V/Cr 、V/(V+Ni)比值说明菱 锰矿的形成经过了锰氧化物或氢氧化物的过程。 3、菱锰矿的提取试验显示，道坨锰矿中菱锰矿的稀土元素经 PAAS 标准化 后其稀土配分曲线呈轻稀土含量少，中稀土富集，重稀土相对中稀土减少的“帽” 式配分模式，Ce 呈正异常，与现代海洋中锰结核的稀土元素特征相似，从而也 说明菱锰矿的形成经过了锰氧化物或氢氧化物的阶段。 4、大塘坡组底部含锰黑色页岩 Re-Os 同位素分析显示，大塘坡组底部的年 龄是 660.6 ± 7.5Ma，该年龄与邻区的大塘坡组底部的锆石凝灰岩的年龄一致。 因此 660.6 ± 7.5Ma 为锰矿的成岩年龄，其约束了铁丝坳冰期的上限年龄。通过 锰矿的成矿年龄去计算锰矿形成时的 187Os/188Os 初始比值，以及 Eu 的正异常， 揭示道坨锰矿中锰有海底热液的来源。 关键词：道坨锰矿，菱锰矿、提取、稀土元素、Re-Os 3 Abstract Black shale in Datangpo formation of the Neoproterozoic Nanhua perios is an important manganese formation, discovered in 2010 in the manganese containing layers of the Guizhou Dao Tuo manganese ore has become Chinas largest manganese deposit. In this paper, through the analysis of the Dao Tuo manganese manganese bearing rock series family elements, trace element analysis, ion microprobe analysis, extraction and analysis of analysis of manganese ore of manganese carbonate and Re-Os isotope, explore the formation environment, ore forming process, forming time and material sources, preliminary get the following conclusions: 1、Manganese ore samples in Al/Ti ratio shows that Mn is mainly in the far from terrigenous, forming a greater depth of water in the.The ratio of Fe/Mn show that the Mn is in the appropriate redox conditions of formation. 2、Co, Mo, V/Cr, Th/U element enrichment and V/ (V+Ni) ratios show the formation of rhodochrosite through the process of manganese oxide or hydroxide. 3、Display the extraction experiment of rhodochrosite, rare earth elements in Dao Tuo manganese rhodochrosite by PAAS standard after the REE distribution curve of light rare earth content of less rare earth enrichment, heavy rare earth relative rare earth reduced cap type distribution pattern, positive Ce anomaly, similar