过渡金属催化多取代功能烯烃制备的研究-有机化学专业论文.docx

II万方数据 II 万方数据 万方数据 万方数据 ABSTRACTABSTRACT ABSTRACT ABSTRACT We focused our study on transition·-metal·-catalyzed the synthesis of highly substituted functional alkenes，mainly including the following three parts in our work． Part 1：Preparation of highly substituted够-Acylamino)acrylates via iron—catalyzed alkoxycarbonylation of N-vinylacetamides with carbazates． We have developed an iron—catalyzed alkoxycarbonylation reaction of N-vinylacetamides with carbazates under simple and mild reaction conditions．Various acyclic and cyclic N-vinylacetamides as starting materials were found to be tolerated