含氟丙烯酸酯共聚物的合成与环氧树脂涂料共混改性研究-应用化学专业论文.docxVIP

STUDY ON SYNTHESIS OF PERFLUOROALKYL ETHYL ACRYLATE COPOLYMER AND ITS APPLICATION IN EPOXY COATINGS ABSTRACT Epoxy coating is widely used in the field of anticorrosion because of its excellent mechanical properties, adhensive properties, anticorrosive properties, and low Shrinkage. Recently, the material with hydrophobic properties has attached more attentions because of its great value in many fields. Applying the hydrophobic material to the epoxy coating will improve the repellence of water and enhance the anticorrosion of the coating. Both the chemical structure and microstructures are two key factors for surface properties of material. It is known to all that fluorinated polymer has unique properties，such as low surface energy, outstanding water and oil repellent properties, self-cleaning properties and excellent chemical and thermal stability. So it is widely used in the filed of coating and management of fabric. In this paper, epoxy resign with excellent surface properties was prepared by blending with perfluoroalkyl ethyl acrylate copolymer（DFMA-co-MMA-co-SA）and nano- SiO2, Perfluoroalkyl ethyl acrylate copolymer（DFMA-co-MMA-co-SA）was synthesized by emulsion polymerization and were characterized by 1H-NMR and FTIR. The hydrophobicity of modified epoxy coatings was significantly improved, when the dosage of P(DMFA-MMA-SA) was 10wt%, the surface energy of epoxy varnish and epoxy paints was reduced to 16.4mN·m-1 and 4.5 mN·m-1, and the contact angle for water was 111°and 136°, respectively. Epoxy coating still retained good mechanical properties and its anticorrosive properties was greatly improved. Nanometer SiO2 prepared by catalytic hydrolysis was added to modified the epoxy coating to construct the roughness. SEM images showed that coatings surface with porous network micrometer-nanometer-scale binary structure was fabriced.When the amount of nanometer SiO2 II was 10wt%, the water contact angle was 144° and the oil contact angle was about to 70°. KEY WORDS: