硅铬绿新型陶瓷颜料的研制及呈色机理的研究-材料学专业论文.docxVIP

摘 摘 要 摘 要 绿色陶瓷颜料，在制备中大多以氧化铬作为发色剂，并引入相应数量的无机矿 物原料及氧化物配制而成。论文综述了绿色陶瓷颜料的现状及存在的问题。利用包 覆型色料呈色的稳定性，采用固相法和液相法两种方法制备包覆型硅铬绿色料． 实验过程中探讨了硅铬绿色料合成的工艺条件，确定最佳的工艺参数．在固相 法中，首次采用无定型二氧化硅即白碳黑为包覆物，通过控制焙烧温度和保温时 间，添加不同矿化剂种类及其含量等措施调整色料的最佳颜色．在液相法中，研究 了悬浮渡的固舍量、水硅比、催化剂的种类及浓度等因素对颗粒表面包膜的影瞎。 采用激光粒度仪、X射线衍射仪、扫描电镜、电子能谱等方法对包覆的效果进行了 表征分析，同时采用色度色差计对色料及色釉进行了颜色的测量分析． 研究结果表明：在固相合成法中，选用无定型二氧化硅即白碳黑和氧化铬粉为 主要原料，且无定型二氧化硅／氧化铬在3～4之间；选用硼酸为矿化剂，加入量在 6％～8％；煅烧1300℃，保温3h制备的色科呈色效果最好．在液相合成法中，加 入3％～6％的氨水作催化剂；将正硅酸乙酯和氨水分别用异丙醇稀释后，同时缓慢 滴加；并且控制反应体系水硅比在45左右，可得到膜厚均匀致密的包覆粒子，经过 高温煅烧后得到包覆型的硅铬绿色料，并且在乳浊釉中的应用效果较好。 图22表23参45 关键词t硅铬绿色料；包覆：呈色机理 分类号t TQl74 河北理工大学硕士学位论文Abstract 河北理工大学硕士学位论文 Abstract Green ceramic pigments ale maked叩by using chrome oxide as coloring agent, adding a quantity of inorganic raw mineral materials and o)【id铭．This paper overviews the present situation and open questions of the green ceramic pigments．Because of color stability of coated pigment,the coated silicon-chrome-green pigment is synthesized by solid phase synthesis and liquid phase synthesis． In the experiment process,the technological conditions of synthesis silicon-chrome- green pigment雠studied and the best technological permneters arc determined．In the solid phase synthesis,the good color can be adjusted by controlling baked temperature and heat preservation time,adding the different mineralizers and different contents and firstly using undefined silicon dioxide as coming matter．In the liquid phase synthesis，Some factols，such as the solid phase concentration of snspendmg liquid,the proportion of distilled water to ethyl estcr orthosilicate，the type ofthe catalyst and its concentration，that car affect the quality ofthe coating film arc studied．On the other hand,the quality ofthe coating film is characterized witll laser partial size analysis．Scanning electronic microscope，X-ray diffraction analysis,electron spectrometer and 50 OIL And the color measurement ofpigment and glaze colors arc tested by the Colorimeter． The experimental results show that,in t