甲氯在土壤中吸附常数的测定.pdf

1999 5 ENVIRONM ENTA L SCIENCE May , 1999 2 4 * * * 渠　锋　莫汉宏 　安凤春　杨克武 ( , 100085) 2 4 3 . Fr undlich , 2 4 108. 2 4 , . 2 4 , , , , , . Determination of Adsorption Constant of MCPA in Soil s F ng QuHanhong Mo F ngchun AnK w u Yang ( R s arch C nt r for Eco-Environm ntal Sci nc s, Chin s Acad my of S i n c s, B ijing100085, Chin a) Abstract A study on th adsorption of 2-m thy 1-4-chloroph noxyac tic acid ( MCPA) on thr diff r nt soils w ith diff r nt cont nt s of organic m att r w as p rform d. Adsorption isoth rms w r obtain d using batch qui- librium m thod, and adsorption constant w r calculat d. Th valu of organic carbon adsorption constant of MCPA in soil was 108. It is on mol cular lay r adsorption and b longs to physical adsorption. Keywords MCPA , soil, adsorption constant, adsorption isot h rms, on mol cular lay r adsorpt ion, physical adsorption. 2 4 ( 2-m thyl-4-chloroph noxyac tic 210 , 200 , acid, M CPA) . 2 4 220 ; K-D ; QZX-C ; , LXJ-64-01 . [ 13] , 99% ; ; , . H lu g M CPA : M CPA , , ; [ 1] . 2. 43. 02. 9% K d = 0. 70. 91. 0 . Gonzal z-Pradas , 1 . K f = 0. 21. 8[ 2] . M ill r 1/ % : f = 0. 24 K [ 3] 2. 21 . pH 5. 44 7. 85 8. 50 OM 1) 6. 50 1. 66 1. 16 10. 0 73. 2 60. 0 , , 68. 0 15. 0 14. 0 M CPA