环碳酸酯的合成研究-化学、有机化学专业论文.docx

兰州大学博士学位论文闫鹏 兰州大学博士学位论文闫鹏 中文摘要 关键词：二氧化碳，环氧化合物，环碳酸酯，手性聚SalcnCo催化剂，手性 拆分，均相催化，多组分反应 ABSTRACTCyclic ABSTRACT Cyclic carbonates，as one of products of C02 chemistry,are attractive and important compounds in a variety of chemical research fields．such弱polar aprotie solvent，intermediate in organic synthesis，precursors for polymeric materials such硒 polycarbonates。This thesis aims at the studies on the asymmetric synthesis and multi．component synthesis of cyclic carbonate，which consists of the following four chapters． Chapter l：The application and synthesis of cyclic carbonate are reviewed，and the development in the green synthesis of cyclic carbonate via C02 cycloaddition to epoxide is briefly introducted．The design and application of polymer catalyst on the asymmetric synthesis also are concluded in this chapter． Chapter 2：Based on the concept of“one-phase catalysis and two。phaSe separation’，we developed four new polymer BINOL—Salen—Co(III)X catalysts with an auxiliary dliral site,and problems encountered in the synthesis of the catalyst are presented and discussed in detail． Chapter 3：Four new chiral polymers of BINOL-Salen-cobalt(III)salt complexes have been applied to the direct fabrication of chiral propylene carbonate from racemic propylene oxide and the hydrolytic kinetic resolution of racernic propylene．The experiment investigated the effect of different clliral catalyst,CO—catalyst，counterious， reaction temperature in clliral cyclic carbonate formation．The chirality of the BINOL fragment haS an important influence 011 the optical selectivity of Salen。Co(III)X complexes．The catalysts could be readily recovered and be repeatedly used without loss of either activity or enantioselectivity． Chapter 4：Inspired by the mechanism of the Darzens reaction and based on 兰州大学博上学位论文闷鹏mechanism 兰州大学博上学位论文闷鹏 mechanism considerations of cyclic carbonate synthesis，we design a three—component cyclization reaction for polysubstituted cyclic carbonate synthesis in a single operation fro