混凝-Fenton氧化法处理印染废水试验研究-市政工程专业论文.docxVIP

摘要本文总结了国内外印染废水处理技术的现状和发展趋势，分析讨论了混凝法、 摘要 本文总结了国内外印染废水处理技术的现状和发展趋势，分析讨论了混凝法、 Fenton氧化法处理印染废水的机理。 本研究分别以水溶性染料茜素红、分散性染料甲基红配置的溶液作为模拟的 印染废水，先对其进行混凝处理，然后采用Fenton试剂氧化法处理。通过单因素 试验，分别得到混凝和Fenton氧化法体系中各因素与CODc，和色度去除率的关系 曲线。研究各因素，如混凝剂种类及其投加量、pH、温度、搅拌速度和时间等对 混凝效果的影响，同时研究各因素，如H202投加量及其投加方式、Fe2+投加量、 pH、温度、反应时间、紫外光等对Fenton氧化法处理效果的影响，并探讨各影响 因素的作用机理与规律，同时还比较混凝与Fenton氧化法对两种染料去除率的不 同，且分析其原因。 试验结果表明，混凝处理最佳条件为：在茜素红溶液中，混凝剂PAC和助凝 剂PAM的投加量分别为300mg／L和lOmg／L，初始pH值为lO，快速搅拌2rain， 慢速搅拌1 5min，温度为40℃；在甲基红溶液中，混凝剂PAC和助凝剂PAM的 投加量分别为50mg／L和2mg／L，初始pH值为10，快速搅拌2min，慢速搅拌15min， 温度为40℃。Fenton氧化法处理的最佳操作条件为：在茜素红和甲基红溶液中， 过氧化氢加入量均为0．5mL／L，Fe2+投加量浓度均为150mg／L，反应初始pH值均 为3．O，反应时间均为30min。在最佳操作条件下，经混凝和Fenton氧化处理后， 两种染料降解率都取得一定的效果，水溶性染料茜素红色度和CODCf去除率达到 88．2％、79．6％，分散性染料甲基红色度和CODc，去除率达到75．3％、70。1％。 关键词：印染废水；混凝；Fenton；水溶性染料；分散性染料 ABSTRACTThis ABSTRACT This paper has summarized the current status and trend of dyeing wastewater treatment teclmologies，analyzed and discussed the mechanism of treating dyeing wastewater by coagulation and Fenton oxidation． This study with water-soluble dye alizarin red，methyl red dye dispersion solution configured as a simulated dyeing wastewater,The dyeing wastewater is treated by Fenton oxidation process after coagulation pretreatment．Through analyzing single factor experiments，the realation clll-ve were obtained，which between influence factors and CODer removals by coagulation and Fenton reagent process system．The effecting factors on the coagulation，such as the type and dosage of coagulant,pH，temperature,stirring speed and time were studied，while the various effecting factors on the Fenton’S oxidation process，such as H202 dosage and dosing method，Fd+dosage，pH，temperature,reaction timeand UV were studied，It is also compared、vim the Fenton reagent oxidation coagulation on removal of two different dyes，and analysis of its causes． The results show that,The best conditions for coagulation ale as follows：in the alizarin red solution,adding of PAC=300mg／L；adding of PAM=10mg／L；pH=10；T=40。C；fast