应用超重力旋转填充床进行二氧化碳捕获与炉渣-中国鑛冶工程学会.PDF

應用超重力旋轉填充床進行二氧化碳捕獲 與爐渣安定化之績效評估 Pe rf o rma nce Ev a luat io n of us ing a Rot at ing Pac ked Bed f o r Simultaneous CO2 Capture and Steel Slag Stabilization 1 2 3 4 S.Y. Pan, P.C. Chiang, E.E. Chang, Y.H. Chen A great amount of CO2 and alkaline wastes have been generated from iron and steel making industry for many years. The industrial wastes such as basic oxygen furnace slag (BOFS) and cold-rolling mill wastewater (CRMW) should be treated and stabilized before discharging or reutilization. It was noted that the alkaline wastes generated from steelmaking industry could be utilized for CO2 capture via carbonation process. Our study showed that CO2 capture by accelerated carbonation of BOFS in a rotating packed bed (PRB) was found to be superior to that in the traditional reactors due to the relatively short reaction time at ambient temperature and pressure. The obj ectives of this study were to ( 1) evaluate the performance of using the CRMW as the liquid phase for increasing the overall carbonation efficiency and reducing the fresh resource con sumption ; (2) characterize the reaction product u sing thermo-chemical analy ses, scanning electron microscope X (SEM) and X-ray diffraction (XRD) ; and (3) assess the potential for utilization of carbonated BOFS as Green Cement. 關鍵詞： Key words: carb on ati on ; b a si c oxy g en fu r n ace sl ag ; c o l d -r o l l i n g m i l l w a st ew at er ; m at er i a l