燃烧中气化半焦孔隙结构特性变化试验研究-中国电机工程学报.PDFVIP

第 32 卷 第 11 期 中 国 电 机 工 程 学 报 Vol.32 No.11 Apr.15, 2012 2012 年 4 月 15 日 Proceedings of the CSEE ©2012 Chin.Soc.for Elec.Eng. 35 0258-8013 (2012) 11-0035-06 TK 123 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 燃烧中气化半焦孔隙结构特性变化实验研究 孙锐，张鑫，Leungo Kelebopile ，廖坚，吴少华 (哈尔滨工业大学能源科学与工程学院，黑龙江省 哈尔滨市 150001) Experimental Study on Pore Structure Changing of Gasified Coal Char Under Combustion SUN Rui, ZHANG Xin, Leungo Kelebopile, LIAO Jian, WU Shaohua (School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang Province, China) ABSTRACT: The combustion characters and pore structure 要由焦炭本征反应活性决定。 changing of the gasified coal char obtained from the secondary 关键词：气化半焦；孔隙结构；比表面积；燃烧反应速率 cyclone of the Jincheng industrial gasifier were experimental studied at high temperature in a simulator of high-temperature 0 引言 entrained flow reactor. Gasified Chars were burned at the temperature of 1273 and 1573K, the oxygen contain of 5% and 加压流化床气化炉由于可以气化高灰熔点、低 20% and sampled along the reactor at different axial residence 挥发分煤种，具有较强的煤种适应性。但气化过程 time. Automatic adsorption instrument (ASAP 2020) was 中产生大量固体飞灰即气化半焦，其含碳量往往较 employed to measure absorption isotherms of sampled chars. 高，引起气化炉效率降低，通过高温燃烧方式来燃 Cryogenic nitrogen absorption isotherms, parameters such as 尽半焦中残碳回收热量是提高碳的转化率的一种 BET specific surface area, BJH pore volume and average pore 好办法。气化飞灰孔隙结构对其燃烧特性具有重要 diameter were measured and analyzed. Surface morphology of the char was further studied by