水与非水磷酸体系质子电导率-JournalofNortheasternUniversity.PDF

第30 卷第5期 东 北 大 学 学 报 ( 自 然 科 学 版 ) V ol30, No. 5 2 00 9 年 5 月 Journal of Nor heas ern U niversi y( N a ural Science) M ay 2 0 0 9 车全通, 王 东, 吕笑梅, 何荣桓 ( , 110004) : , , . , ( ) - , ; , . , . - , , . : ; ; ; ; : O 646 . 1 : A : 1005- 3026( 2009) 05- 0757- 04 Proton Conductivities of Phosphoric Acid Based Hydrous and Anhydrous Systems CH E Quan-tong , WA N G Dong , L X iao-mei , H E Rong-huan ( School of Sciences, Nor heas er n U niversi y , Sheny ang 110004 , China. Corresponden : HE Rong- huan, E- mail: herh @ mail. neu. edu. cn) Abstract : Imidazole and py ridine were mixed w i h pure phosphoric acid o form anhydrous pro on conduc ing elec roly e. Conduc ivi ies of phosphoric acid based anhydrous solu ions and pro on ransfer mechanism w ere inves iga ed for he feasibili y ha he ni rogenous he erocyclic compounds become he carrier for pro on ransfer under anhydrous condi ions. T he resul s indica ed ha he viscosi y of he anhydrous sys em has a signif ican inf luence on he pro on mig ra ion. T he ni rogenous he erocyclic compounds could no ac as w a er molecules o decrease bu increase he viscosi y of phosphoric acid. T he resul s of conduc ivi y show ed ha he pro on ransferabili y due o sel-f ioniza ion and self- dehydra ion of phosphoric acid is superior o ha of bo h phosphoric acid and ni rogenous he erocyclic compounds. As o he im idazole- phosphoric acid aqueous solu ions, i s conduc ivi y rela es o he number of m igra ing ions and m igra ion ra e in addi ion o he viscosi y of he sys em. Key words: pro on conduc or; conduc ivi y; anhydrous pro