粉煤灰的矿物学性质研究-洁净煤技术.PDF

　 第21卷第4期 洁净 煤 技 术 Vol．21　 No．4　 　 2015年 7月 Clean Coal Technology July　 2015　 粉煤灰的矿物学性质研究 赵　 永　 彬 (北京低碳清洁能源研究所 功能材料研发中心,北京　 102211) 摘　 要:为了拓展粉煤灰综合利用途径,提高粉煤灰产品的附加值,采用X射线衍射(XRD)分析方 法,研究神华电厂粉煤灰的矿物相组成及其晶相结构。 研究表明:神华电厂粉煤灰由非晶质玻璃体和 晶质矿物相组成,通过结晶度模拟计算可知非晶质玻璃体含量在35% ~70%,进一步分析发现其矿 物相以莫来石相(7% ~52%)、石英相(0 ~22%)为主,还包括石灰相、磁铁矿相、赤铁矿相、硬石膏 相、钙长石相和钙铝黄长石相等。 此外,进一步分析了燃煤组成及燃烧方式对矿物组成差异的影响, 从而为了解粉煤灰的特性及其高附加值利用提供理论基础。 关键词:粉煤灰;矿物组成;晶相结构;综合利用 - - - 中图分类号:X773　 　 　 文献标志码:A　 　 　 文章编号:1006 6772(2015)04 0112 05 Research on mineralogical properties of fly ash ZHAO Yongbin - - (PerformanceMaterials R D Center,National Institute of Clean and Low Carbon Energy,Beijing　 102211,China) Abstract:To expand comprehensive utilization of fly ash,andfurther enhancetheaddedvalueoffly ashproducts,themineral composition - and crystal structure of fly ash from Shenhua power plant was analyzed by X ray diffraction (XRD) in this article.The results showed that,the mineral composition of fly ash was composed of amorphous and crystalline structure.Amorphous phase content ranged from 35% to70% by crystallinity simulation calculation,and further found that mineral phase of fly ash mainly included mullite (7% ~52%), quartz (0~22%),and also somelime,magnetite,hematite,gypsum,anorthite,gehlenite,etc.In addition,the influenceof coal composition and combustion mode on mineral composition of fly ash further was researched.Therefore,it was easy to learn about the cha