Li2O和B2O3对含稀土氧化物结晶器保护渣结晶相的影响.pdf

34 3 Vol. 34, No. 3 2 0 0 6 3 JOURNAL OF TH E CH INESE CERAMIC SOCIETY March, 2006 Li2 OB2O3 简 报 王德永, 姜茂发 ( , 0004) : Li O B O , , , Li O 2 2 3 2 3 B O : , , 2 3 ; , , , ; B O L i O , , , 2 3 2 : ; ; ; : T G 46. 45 : A : 0454 5648( 2006) 03 0366 05 EFFECTOFLi2OAND B2O3 ON CRYSTALLIZATION PHASES OF MOLD FLUXES BEARING RARE EARTH OXIDES WA N G Dey ong , J I A N G M aof a ( College of Materials M et allurgy , Northeast ern Universit y, Shenyang 0004, China) Abstract: The formation condition of slag film w as simulated by adding some Li O and B O into t he mold powder as new flu- 2 2 3 xes. T he effect of Li O and B O doping on the crystallization phase composition of mold f luxes bearing rare earth oxide w as in- 2 2 3 vest igated by lithofacies and energy chart analysis in scanning electron microscopy. The results show that doping rare earth oxides can restrain the formation of glass phase, accelerate the growt h of cuspidine phase and increase the crystallizat ion ratio of mold fluxes. When the content of rare earth oxides reaches a certain value, RE O CaO 2SiO phase w ill be formed in the 2 3 2 crystallization minerals of mold fluxes and un-dissolved parts w ill be separated out from mold f luxes w ith the increase of rare earth oxide. Adding a small amount of