化学镀镍-中国有色金属学报.PDFVIP

第 18 卷第 6 期 中国有色金属学报 2008 年 6 月 Vol.18 No.6 The Chinese Journal of Nonferrous Metals Jun. 2008 文章编号：1004-0609(2008)06-1105-05 化学镀镍-钴-铁-磷镀层的结构和磁性能 王森林，战俊杰 (华侨大学 材料科学与工程学院 福建省高校功能材料重点实验室，泉州 362021) 摘 要：采用 H3BO3 为缓冲剂、柠檬酸钠为络合剂，在弱碱性体系中化学沉积 Ni-Co-Fe-P 合金，运用能谱分析 仪(EDS)、扫描电镜(SEM)和 X 射线衍射仪(XRD)研究镀液 pH 值对合金结构的影响。结果表明，随着镀液 pH 值 增大，镀层中 Fe 和 Co 含量呈增加趋势而 Ni 和 P 含量趋于减少；镀层表面圆形颗粒呈密堆积，且随着镀液 pH 值的增加，圆形颗粒的粒径减小；镀态镀层呈非晶态结构。镀层在 266.9 ℃晶化产生Fe-Co (Pm3m)相，在 389.6 ℃ 生成亚稳相Ni P (R )和 Co Fe (P )相，随后在 500 ℃进一步晶化形成Ni P (I-4)和 Ni (F )相。随着热处理温 8 3 3C 3 7 m3m 3 m3m 度的升高，合金的饱和磁化强度和矫顽力呈增加趋势。 关键词：Ni-Co-Fe-P 合金；化学沉积；热处理；磁性能 中图分类号：O 646 文献标识码：A Structure and magnetic performances of Co-Ni-Fe-P alloy plated by electroless deposition WANG Sen-lin, ZHAN Jun-jie (The Key Laboratory for Functional Materials of Fujian Higher Education, College of Materials Science and Engineering, Huaqiao University, Quanzhou 362021, China) Abstract: Electroless Ni-Co-Fe-P alloys were deposited from a soft alkaline bath, containing boric acid as a buffer agent and sodium citrate as a complexing agent. The effect of the bath pH value on the coating structure was investigated by energy-dispersive X-ray spectral analysis (EDS), scanning electron microscope (SEM) and X-ray diffractrometry (XRD). As a result, with the increase of the bath pH value, the iron and cobalt contents of the deposit increase basically, while the nickel and phosphorus contents decrease