高速粉碎机作用下的电路板真空热解渣破碎特性-环境工程学报.PDFVIP

第 11卷　 第6 期 环 境 工 程 学 报 Vol. 11,No.6 2 0 1 7 年 6 月 Chinese Journal of Environmental Engineering Jun . 2 0 1 7 高速粉碎机作用下的电路板真空热解渣破碎 特性 ∗ 龙来寿 ,李建渠 韶关学院化学与环境工程学院,韶关 512005 摘　 要　 首先利用高速粉碎机对大颗粒废弃电路板真空热解渣进行破碎处理,然后采用筛分和颗粒计数法研究破碎产物 的破碎规律与解离特性。 结果表明,大颗粒废弃电路板真空热解渣在破碎过程中存在着显著的选择性破碎,金属铜主要分 布在较粗粒级产物中,玻璃纤维和炭黑则主要分布在较细粒级产物中,并且铜能在较大粒级上实现充分解离;98.64% 的铜 分布在粒级为0.45 ~4.0 mm 的破碎产物中,而92.05%的玻璃纤维和炭黑分布在粒级为 -0.45 mm 的破碎产物中;当粒级 为 -2.0 mm 时,铜的解离度达到 100%。 关键词　 废弃电路板;热解渣;破碎;解离 中图分类号　 X705　　 文献标识码　 A　　 文章编号　 1673-9108(2017)06-3785-04　　 DOI　 10.12030/ j.cjee.201610082 Crushing characteristics of vacuum pyrolysis residue of waste printed circuit boards under action of high-speed pulverizer ∗ LONG Laishou ,LI Jianqu College of Chemistry and Environmental Engineering,Shaoguan University,Shaoguan 512005,China Abstract　 The large vacuum pyrolysisresidue particles of waste printed circuit boardswere firstly crushed by u- sing high-speed pulverizer. Then the screening and particle counting method were employed to study the crushing laws and liberation characteristics of the crushed product. The results showed that there was significant selectivity crushing in the crushing process. The copper was mainly distributed in the coarse fraction and the glassfiber and carbon were mainly distributed in the fine fraction. And the copper can be sufficiently liberated on larger grain size. The mass distribution rate of copper is 98.64% for crushed products with grain size of 0.45 to 4.0 mm. The mass distribution rate of glass fiber and carbon is 92.05% for crushed products with grain size of -0.45 mm. The liberation degree of copper is 100% for crushed products with grain size of -2.0 mm. Key words　 waste printed circuit boards;pyrolysis residue;crushing;liberation 　 　 废弃电路板(WPCB)作为一种废弃数量大、再资源化价值高和环境污染严重的电子废弃物,是电子废 [1-2] 物中最复杂、最难处理的危险固体废物 。 因此,