钛酸锂锂离子电池极材料研究评述.docVIP

Li4Ti5O12（钛酸锂）锂离子电池负极材料研究评述 课程编号 07S18C0110 姓名 薛燕红 学号 201120181037 班级 SJ1159 专业 材料物理与化学 Li4Ti5O12（钛酸锂）锂离子电池负极材料研究评述 姓名：薛燕红 学号：201120181037 班级：SJ1159 摘要:锂作为电池材料的研究始于1912年，锂一次电池的研究始于20世纪50年代。但直到1973年SAFT研制出第一个一次锂电池才使得锂电池商业化。锂一次电池是用金属锂作负极，锂盐的有机溶剂为电解液，SO2，MnO2,SOCl2等作为正极的电池体系。金属锂一次电池相对传统的电池具有工作电压高、比能量大、重量轻等优点，因此在一些对能源要求较高的设备上得到广泛的应用。金属锂二次电池出现于八十年代中期，以金属锂片做负极，但由于金属锂电极表面电位分布不均匀，负极锂经过多次充放电后，锂表面容易形成多孔结构和锂枝晶，有可能刺破绝缘隔膜从而引起电池内部短路，以致发生爆炸或起火，安全性能较差。考虑到金属锂作为负极的安全性问题，人们开始寻找其它材料代替金属锂作负极以降低电池的危险性。 关键词:锂离子电池 负极材料 尖晶石 Li4Ti5O12 金属阳离子掺杂 Abstract:Lithium battery materials research began in 1912, the lithium battery began in the 1950s. But it was not until 1973 SAFT developed a lithium battery that makes lithium battery business. Lithium batteries with lithium metal anode, the lithium salt of the organic solvent electrolyte, SO2 MnO2, of SOCl2 as the cathode of the battery system. The lithium primary battery is relatively conventional battery has a high operating voltage, specific energy, light weight and so, therefore been widely used in high energy requirements on the device. The lithium secondary battery in the mid-1980s, the negative lithium tablets, but because of the uneven distribution of the lithium electrode surface potential of the negative electrode of lithium after several charge and discharge, the lithium surface is easy to form the porous structure and lithium dendrite possible to pierce the insulation diaphragm, causing the battery internal short circuit, so as to cause an explosion or fire, the poor safety performance. Taking into account the lithium metal as the security problem in the negative, people start looking for other materials to reduce the risk of battery instead of lithium metal as negative. Key words:Lithium-ion battery; anode material; spinel of Li4Ti5O12; metal cation doping; 1 引言 锂离子电池的成功商品化，关键在于制备可逆的嵌锂化合物代替金属锂负极。理想的负极材料应具备以下几个特点：(1) 具有较高的充放电效率和循环寿命；(2) 首次不可逆容量较小；(3) 具有较高的结构稳定性、化学稳定性和热稳定性且与