臭氧生物活性炭工艺运行中产生溴酸盐的可能性分析.PDF

中国环境科学 2014,34(9) ：2299~2305 China Environmental Science 臭氧生物活性炭工艺运行中产生溴酸盐的可能性分析 刘芳蕾 1,张 冬 2, 吕锡武 1* ( 1.东南大学能源与环境学院,江苏 南京 210096 ；2.南京市自来水总公司,江苏 南 京 210002) 摘要：为合理评估应用臭氧生物活性炭工艺中溴酸盐的生成情况,提出既能保证出 质又能降低溴酸盐超标风险的方案.进行了小试与 中试试验,系统地从原 质和工艺参数两个方面入手,研究水质因素、初始溴离子浓度和臭氧氧化条件等对溴酸盐生成的影响, 同时分析 生物活性炭对溴酸盐的去除能力.结果表明:高初始溴离子浓度水平和臭氧接触程度(Ct 值)促使更多 BrOx- 生成.在相同 Ct 值条件下,升高臭 氧投加浓度可使溴酸盐生成量增高 200%左右.以长江南京段江心洲夹江下游原水进行臭氧生物活性炭深度处理不会产生溴酸盐超标风险. 生物活性炭(BAC)对于溴酸盐去除效果并不明显.运用臭氧生物活性炭工艺进行深度处理时,工艺中应着重注意控制溴酸盐在臭氧化过程 中的生成而非依靠后续生物活性炭将其去除. 关键词：臭氧；生物活性炭(BAC) ；溴酸盐；臭氧投加量 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2014)09-2299-07 1 Possibility analysis for bromate generation during running ozone-biological activated carbon process. LIU Fang-lei , 2 1* ZHANG Dong , LÜ Xi-wu (1.School of Energy and Environment, Southeast University, Nanjing 210096, China；2.Nanjing Water Corporation, Nanjing 210002, China). China Environmental Science, 2014,34(9) ：2299~2305 Abstract ：Laboratory and pilot scale experiments were carried on to assess the formation of bromate during ozone- biological activated carbon (O3-BAC), and further to provide practical parameters for drinking water treatment with low risk of excessive bromate. The effects of initial bromide concentration and oxidation condition on bromate formation were studied, and bromate removal capability of the O3-BAC was also evaluated. Results showed that the concentration of bromide ion and ozone exposure level (Ct value) could impose a positive impact on bromate formation. Under the same value of Ct, an increasing ozone concentration would