氧化锌基纳米材料光学与非线性光学性质稳定性的分析.pdfVIP

摘 要 近年来，ZnO 作为一种新型的波长较短的半导体激光材料被大众人群所知晓， 由于ZnO 其自身所具有的十分优良的电学性能以及光学性能，所以时下被广泛应 用于各类型的光学器件、压电器件以及场发射器件。自此，ZnO 系材料成为材料 科学的研究焦点，同样也是基础科学和应用科学的重中之重。 本文制备的Fe 、Co 掺杂ZnO 纳米材料是采用了改进的微乳液法制备的，并且 对所制备材料的结构和形貌分别使用 X 射线衍射（XRD ）及扫描电子显微镜的 （SEM）进行了表征。为了明确温度对ZnO 纳米材料光学性质的影响，使用自组 装温控仪进行降温操作，对所制备的ZnO 及Fe 、Co 掺杂ZnO 材料进行了光学性 质的对比研究，得到了在改变不同温度的条件下样品ZnO 及分别用Fe 、Co 掺杂所 得的样品 ZnO 纳米材料随温度的改变而发生一系列变化的对比发光光谱。并分析 了Fe 、Co 掺杂导致ZnO 缺陷能级的改变而使得ZnO 发光光谱改变的诸多问题， 进而分析了对ZnO 纳米材料发光特性的影响。 关键词：ZnO 纳米材料； 发光； 温度； 掺杂 ABSTRACT In recent years, the ZnO as a new type of short wavelength of semiconductor laser materials known by people, because the ZnO itself has very excellent electrical properties and optical properties, so they are widely used in all kinds of optical devices, piezoelectric devices and field emission devices. Since then, ZnO materials become the research focus of material science, is the key of the basic science and applied science. In this paper, Fe and Co doped ZnO nanomaterials are prepared by improved microemulsion method. X-ray Diffraction (XRD) and Scanning electron microscope (SEM) are used to explore the structure and morphology of the synthetized nanomaterials. In order to explore the influence of temperature on the optical properties of ZnO nanomaterials, cooling temperature controller is used to realize the temperature variable environment. Photoluminescence experiments are performed to get the optical properties of ZnO nanomaterials and Fe, Co doped ZnO nanomaterials. Compare the results, we get the change of optical spectrum of ZnO and Fe, Co doped ZnO nanomaterials and analyze the defect levels induced by Fe, Co doping and the i