过渡金属铈复合氧化物对碳烟的催化燃烧性能和表征.pdfVIP

30 1 Vo.l 30, No. 1 2010 1 Acta Scientiae Circumstantiae Jan. , 2010 , ,, . 2010. [ J]. , 30( 1): 158- 164 M ingC B, Y eD Q, LiangH, et a l. 2010. Catalytic combustion performance of soot over ceriumbased transition metal composite oxide catalysts[ J]. A cta Scientiae Circumstantiae, 30( 1): 158- 164 1 2, * 3 1 明彩兵, 叶代启 ,梁红, 刘晖 1. 仲恺农业工程学院 环境科学与工程学院, 广州 510225 2. 华南理工大学 环境科学与工程学院, 广州 510640 3. 广州大学 化学化工学院, 广州 510006 : : : : ( FeVM nCoCu), ( H TPR)BETXRD 2 (RS) (XPS). , . , , , . O . II : ; ; ; ; : 2010) 0115807 : X131 : A Catalytic com bustion perform ance of soot over cerium based transition m etal composite oxide catalysts 1 2, * 3 1 M IN Caibing, YE Daiqi , LIAN Hong , LIU Hui 1. College ofEnvironmental Science and Engineering, ZhongkaiUniversity ofAgriculture and Engineering, uangzhou 510225 2. College ofEnvironmental Science and Engineering, South ChinaUniversity ofTechnology, uangzhou 510640 3. College ofChemistry and Chem icalEngineering, uangzhou University, uangzhou 510006 Received 8 March 2009; received in revised form 26 Ausgut 2009; accepted 26 O ctober2009 Abstract: T ransition metal ( Fe, V, M n, Co and Cu) /Ce composite ox ide catalysts were prepared by coprecipitation. The catalytic activity of the catalysts for soot combustion was determ ined by thermogravmi etry (T ). The results show that the added transition metal greatly enhances the catalytic reactivity of ceria. Among the catalysts, the ironcerium composite oxide exhibits the most activity. Catalysts were investigated by techniques such as temperatureprogrammed reduction ( H TPR), B