镁铝氧化物催化生物质衍生物的羟醛缩合研究-化学工艺专业毕业论文.docxVIP

和急 和急 体排 成的 济可 的重要途径，本文研究在水相中加工生物质的衍生物制备液体燃料的新方法。 利用共沉淀法制备镁铝氧化物催化剂，作为生物质的衍生物进行羟醛缩合 反应的催化剂，实验表明反应液的pH值控制是制备催化剂的关键因素，综合 考虑pn维持为11比较合理，利用苯甲酸滴定法测定的催化剂的碱中心数为 0．8159 mmol苯甲酸／g。用一阶导数分光光度法测定糠醛浓度，研究糠醛和丙酮 40℃下在镁铝氧化物催化下的反应动力学，得到的反应动力学方程为：C=Co严 =13．14一’189l‘。不加催化剂时，反应不发生。 40C下镁铝氧化物能够有效催化糠醛和丙酮在去离子水中的羟醛缩合反 应，生成黄褐色的油相产物和深褐色的固体产物。将纤维素的水解液调至中性 后，40℃下镁铝氧化物也能够催化纤维素水解液中的羟醛缩合反应，反应产生 的黑色油相产物用四氢呋喃从黑色固体残渣中抽提。糠醛和丙酮及纤维素水解 液羟醛缩合反应油相产物的红外光谱分析表明，两种产物的结构有相似之处， 不同之处是纤维素水解液羟醛缩合反应油相产物中有较多的羟基。 关键词：生物质；糠醛；羟醛缩合；镁铝氧化物； I AbstractEnergy Abstract Energy resource is all essential material n络ou哟which human society CRB 8ulNive on and develop丽血．The main questions of energy which human beings file facing and urgently need to be solved include the shortage of fossil energy resourcA3s， greenhouse gas emissions on global warming and air pollution on human health and the environment．With a n眠clean and renewable energy substitute traditional fossil fuels to achieve sustainable economic development is an inevitable choice．Clean and renewable substitute for oil from biomass to produce transportation fuels is an important m韶fflB．In this paper,a new method that converts biomass—derived carbohydrates into liquid fuds in water was researched． The Mg-Al oxide catalyst which is used as catalyst in aldol-condensation of biomass-derived is prepared with coprecipitation．The experiment’S result indicates that the pH value of reaction solution is a key factor in the preparation of catalyst and it is reasonable when its value is l 1．With benzoic acid titration the Mg-AJ oxide catalyst’S base centers number is 0．8 1 59 mmol／g．The concentration of furfural is determined in derivative apectrophotometry and reaction kinetic of aldol-condensation of furfural and acetone by M争砧oxide catalyst at 40C is studied．the reaction kinetic equation is c=c0 e-h=13．14一‘1龇．Without catalyst, the reaction does not ood2ur． The Mg-A1 oxide啪be an effective catalyst for aldol—condensation of furfural and acetone at deionized water at 40℃．And the